(-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0^2,6>decan-3-ol

Base Information

Chemical Name:(-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0^2,6>decan-3-ol
CAS No.:84077-37-2
Molecular Formula:C₁₃H₂₀O₃
Molecular Weight:224.3
Hs Code.:

(-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0<sup>2,6</sup>>decan-3-ol

Synonyms:(-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0^2,6>decan-3-ol

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Chemical Property of (-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0^2,6>decan-3-ol

Chemical Property:

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Technology Process of (-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0^2,6>decan-3-ol

There total 1 articles about (-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0^2,6>decan-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 32780-06-6
(5S)-5-(hydroxymethyl)-2-oxo-tetrahydrofuran

: 84077-37-2
(-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0^2,6>decan-3-ol

Guidance literature:: Multi-step reaction with 7 steps

2: cc HCl / methanol

3: pyridine / methanol

4: 25 percent / Irradiation

5: 95 percent

7: 2.) NaBH₄ / 1.)Pd/C in AcOEt; 2.) MeOH

With pyridine; hydrogenchloride; sodium tetrahydroborate; In methanol;
DOI:10.1016/S0040-4039(00)87626-1

Reference yield:

: 84077-37-2
(-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0^2,6>decan-3-ol

: 5208-59-3,13828-08-5,68036-15-7,78148-76-2,92998-16-8,119903-95-6,135355-71-4
(1S,3aS,3bR,6aS,6bR)-1-Isopropyl-3a-methyl-6-methylene-decahydro-cyclobutadicyclopentene

Guidance literature:: Multi-step reaction with 7 steps

1: pyridine / 20.5 h / Ambient temperature

2: 91 percent / 55percent NaH / 1,2-dimethoxy-ethane / 0 deg C, reflux, 19 h

3: 85 percent / LAH / diethyl ether / 2 h / Ambient temperature

4: pyridin / 36 h / Ambient temperature

5: 78 percent / LiAlH₄ / tetrahydrofuran / 1.8 h / Heating

6: 82 percent / p-toluenesulfonic acid / acetone / 23 h / Ambient temperature

7: 98 percent / BuLi / hexane; diethyl ether / 20 h / Ambient temperature

With pyridine; lithium aluminium tetrahydride; n-butyllithium; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; hexane; acetone;

Reference yield:

: 84077-37-2
(-)-(1S,2R,3S,6S,7R)-10-ethylenedioxy-6-methyltricyclo<5.3.0.0^2,6>decan-3-ol

: 5208-59-3,13828-08-5,68036-15-7,78148-76-2,92998-16-8,119903-95-6,135355-71-4
(-)-β-bourbonene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.)tosylation 2.) refluxing DME

2: 85 percent / LiAlH₄

3: 1.) LiAlH₄ 2.) p-TsOH / 2.) acetone

4: 98 percent

With lithium aluminium tetrahydride; toluene-4-sulfonic acid;
DOI:10.1016/S0040-4039(00)87626-1