Technology Process of 13,27-Bis(2,4,6-triphenyl-1-pyridinio)-3,6,9,17,20,23-hexaoxatricyclo<23.3.1.111,15>triaconta-1(29),11,13,15(30),25,27-hexaene-29,30-diol Bis(tetrafluoroborate)
There total 7 articles about 13,27-Bis(2,4,6-triphenyl-1-pyridinio)-3,6,9,17,20,23-hexaoxatricyclo<23.3.1.111,15>triaconta-1(29),11,13,15(30),25,27-hexaene-29,30-diol Bis(tetrafluoroborate) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
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143634-93-9
13,27-Diamino-3,6,9,17,20,23-hexaoxatricyclo<23.3.1.111,15>triaconta-1(29),11,13,15(30),25,27-hexaene-29,30-diol
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143634-95-1
13,27-Bis(2,4,6-triphenyl-1-pyridinio)-3,6,9,17,20,23-hexaoxatricyclo<23.3.1.111,15>triaconta-1(29),11,13,15(30),25,27-hexaene-29,30-diol Bis(tetrafluoroborate)
- Guidance literature:
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With
acetic acid;
In
methanol; dichloromethane;
for 3h;
Ambient temperature;
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143634-95-1
13,27-Bis(2,4,6-triphenyl-1-pyridinio)-3,6,9,17,20,23-hexaoxatricyclo<23.3.1.111,15>triaconta-1(29),11,13,15(30),25,27-hexaene-29,30-diol Bis(tetrafluoroborate)
- Guidance literature:
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Multi-step reaction with 7 steps
1: 1) NaOH / 1) H2O, reflux, 2) reflux, 4 h
2: 79 percent / N-bromosuccinimide, azobisisobutyronitrile / CCl4 / 1.5 h / Heating
3: 55 percent / NaH / tetrahydrofuran / 10 h / Heating
4: 49 percent / LiAlH4 / tetrahydrofuran / 18 h / Heating
5: 81 percent / NaNO3 / concd. HCl / La(NO3)3 / H2O; diethyl ether; CH2Cl2 / 15 h / Ambient temperature
6: 92 percent / H2 / 10percent Pd/C / methanol / 96 h / 760 Torr / Ambient temperature
7: 64 percent / AcOH / CH2Cl2; methanol / 3 h / Ambient temperature
With
hydrogenchloride; sodium hydroxide; sodium nitrate; N-Bromosuccinimide; lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); hydrogen; sodium hydride; acetic acid; lanthanum(III) nitrate;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; tetrachloromethane; diethyl ether; dichloromethane; water;
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143634-95-1
13,27-Bis(2,4,6-triphenyl-1-pyridinio)-3,6,9,17,20,23-hexaoxatricyclo<23.3.1.111,15>triaconta-1(29),11,13,15(30),25,27-hexaene-29,30-diol Bis(tetrafluoroborate)
- Guidance literature:
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Multi-step reaction with 5 steps
1: 55 percent / NaH / tetrahydrofuran / 10 h / Heating
2: 49 percent / LiAlH4 / tetrahydrofuran / 18 h / Heating
3: 81 percent / NaNO3 / concd. HCl / La(NO3)3 / H2O; diethyl ether; CH2Cl2 / 15 h / Ambient temperature
4: 92 percent / H2 / 10percent Pd/C / methanol / 96 h / 760 Torr / Ambient temperature
5: 64 percent / AcOH / CH2Cl2; methanol / 3 h / Ambient temperature
With
hydrogenchloride; sodium nitrate; lithium aluminium tetrahydride; hydrogen; sodium hydride; acetic acid; lanthanum(III) nitrate;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane; water;
