tert-Butyl-[(R)-3-((S)-1,3-dimethyl-2-vinyl-cyclopent-2-enyl)-butoxy]-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-[(R)-3-((S)-1,3-dimethyl-2-vinyl-cyclopent-2-enyl)-butoxy]-diphenyl-silane
CAS No.:119242-27-2
Molecular Formula:C₂₉H₄₀OSi
Molecular Weight:432.721
Hs Code.:

Synonyms:tert-Butyl-[(R)-3-((S)-1,3-dimethyl-2-vinyl-cyclopent-2-enyl)-butoxy]-diphenyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-Butyl-[(R)-3-((S)-1,3-dimethyl-2-vinyl-cyclopent-2-enyl)-butoxy]-diphenyl-silane

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Technology Process of tert-Butyl-[(R)-3-((S)-1,3-dimethyl-2-vinyl-cyclopent-2-enyl)-butoxy]-diphenyl-silane

There total 5 articles about tert-Butyl-[(R)-3-((S)-1,3-dimethyl-2-vinyl-cyclopent-2-enyl)-butoxy]-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 117154-98-0
(R)-3-((S)-1,3-Dimethyl-2-vinyl-cyclopent-2-enyl)-butan-1-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 119242-27-2
tert-Butyl-[(R)-3-((S)-1,3-dimethyl-2-vinyl-cyclopent-2-enyl)-butoxy]-diphenyl-silane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 25 ℃; for 0.25h; Yield given;
DOI:10.1021/ja00180a064

Reference yield:

: 131100-26-0
(R)-3-((S)-1,3-Dimethyl-2-oxo-cyclopentyl)-butyric acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester

: 119242-27-2
tert-Butyl-[(R)-3-((S)-1,3-dimethyl-2-vinyl-cyclopent-2-enyl)-butoxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) KN(SiMe₃)2 / 2.) THF, -78 deg C

2: 87 percent / LiCl, (Ph₃P)4P / 12 h / 65 °C

3: i-Bu₂AlH / tetrahydrofuran / 0 °C

4: imidazole / dimethylformamide / 0.25 h / 25 °C

With 1H-imidazole; (Ph₃P)4P; potassium hexamethylsilazane; diisobutylaluminium hydride; lithium chloride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/ja00180a064

Reference yield:

: (R)-3-((S)-1,3-Dimethyl-2-vinyl-cyclopent-2-enyl)-butyric acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester

: 119242-27-2
tert-Butyl-[(R)-3-((S)-1,3-dimethyl-2-vinyl-cyclopent-2-enyl)-butoxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: i-Bu₂AlH / tetrahydrofuran / 0 °C

2: imidazole / dimethylformamide / 0.25 h / 25 °C

With 1H-imidazole; diisobutylaluminium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/ja00180a064