D-[6-13C]FRUCTOSE

Base Information

• Chemical Name: D-[6-13C]FRUCTOSE
• CAS No.: 312623-94-2
• Molecular Formula: C₆H₁₂O₆
• Molecular Weight: 186.092
• Mol file: 312623-94-2.mol

Synonyms:D-[6-13C]FRUCTOSE;D-FRUCTOSE-6-13C, 99 ATOM % 13C

Chemical Property of D-[6-13C]FRUCTOSE

Chemical Property:

• Melting Point: 119-122 °C (dec.)(lit.)
• PSA: 110.38000
• LogP: -3.21980

Purity/Quality:

99% ^*data from raw suppliers

D-[6-13C]FRUCTOSE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of D-[6-13C]FRUCTOSE

There total 9 articles about D-[6-13C]FRUCTOSE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

[UL-13C6]-6-MOM-methyl-1,3-di-O-isopropylidene-α-D-tagatofuranoside → D-[UL-13C6]tagatopyranose (312623-94-2)

Guidance literature:

With hydrogenchloride; In 1,4-dioxane; water; at 20 ℃; for 24h;

DOI:10.1016/j.carres.2021.108377

Reference yield: 64.0%

C6(13)C6H20O6 → D-allulose-13C6 (312623-94-2)

Guidance literature:

With acetic acid; at 60 ℃; for 14h;

DOI:10.1246/cl.210181

Reference yield:

D-fructose-13C6 (312623-94-2) → D-allulose-13C6 (312623-94-2)

Guidance literature:

Multi-step reaction with 4 steps

1: perchloric acid / acetone / 17 h / 0 - 20 °C

2: dipyridinium dichromate; acetic acid / dichloromethane / 19.5 h / 20 °C / Molecular sieve

3: sodium tetrahydroborate / ethanol / 1 h / 0 °C

4: acetic acid / 14 h / 60 °C

With sodium tetrahydroborate; dipyridinium dichromate; perchloric acid; acetic acid; In ethanol; dichloromethane; acetone;

DOI:10.1246/cl.210181