(+/-)-7-benzyl-6,6-dimethyl-6a,7-dihydro-6H-5-thia-7-azabenzo[4,5]pentaleno[2,1-a]naphthalene

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Chemical Name:(+/-)-7-benzyl-6,6-dimethyl-6a,7-dihydro-6H-5-thia-7-azabenzo[4,5]pentaleno[2,1-a]naphthalene
CAS No.:1314684-15-5
Molecular Formula:C₂₇H₂₃NS
Molecular Weight:393.552
Hs Code.:

Synonyms:(+/-)-7-benzyl-6,6-dimethyl-6a,7-dihydro-6H-5-thia-7-azabenzo[4,5]pentaleno[2,1-a]naphthalene

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Chemical Property of (+/-)-7-benzyl-6,6-dimethyl-6a,7-dihydro-6H-5-thia-7-azabenzo[4,5]pentaleno[2,1-a]naphthalene

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Technology Process of (+/-)-7-benzyl-6,6-dimethyl-6a,7-dihydro-6H-5-thia-7-azabenzo[4,5]pentaleno[2,1-a]naphthalene

There total 2 articles about (+/-)-7-benzyl-6,6-dimethyl-6a,7-dihydro-6H-5-thia-7-azabenzo[4,5]pentaleno[2,1-a]naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 1314684-01-9
(1-benzyl-1H-indol-3-yl)(2,2-dimethyl-2H-thiochromen-4-yl)methanol

: 1314684-15-5
(+/-)-7-benzyl-6,6-dimethyl-6a,7-dihydro-6H-5-thia-7-azabenzo[4,5]pentaleno[2,1-a]naphthalene

Guidance literature:: With scandium tris(trifluoromethanesulfonate); In benzene; at 20 ℃; for 0.2h; Inert atmosphere;
DOI:10.1039/c0ob00892c

Reference yield:

: 154324-94-4
4-bromo-2,2-dimethyl-2H-thiochromene

: 1314684-15-5
(+/-)-7-benzyl-6,6-dimethyl-6a,7-dihydro-6H-5-thia-7-azabenzo[4,5]pentaleno[2,1-a]naphthalene

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: scandium tris(trifluoromethanesulfonate) / benzene / 0.2 h / 20 °C / Inert atmosphere

With n-butyllithium; scandium tris(trifluoromethanesulfonate); In tetrahydrofuran; hexane; benzene; 2.1: Nazarov cyclization;
DOI:10.1039/c0ob00892c