3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate

Base Information

Chemical Name:3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate
CAS No.:1241376-04-4
Molecular Formula:C₂₅H₂₉N₃O₉
Molecular Weight:515.52
Hs Code.:

Synonyms:3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate

Suppliers and Price of 3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate

There total 1 articles about 3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranose

: 120870-47-5
2-(1-hexyn-1-yl)benzoic acid

: 1241376-04-4
3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate

Guidance literature:: With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine; In dichloromethane; for 5h;
DOI:10.1039/c0cc00566e

Reference yield: 96.0%

: 1140972-41-3
C₃₀H₂₉NO₉

: 1241376-04-4
3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate

: 1185868-59-0
C₄₂H₄₄N₄O₁₆

Guidance literature:: With triphenylphosphinegold(I) triflate; In diethyl ether; dichloromethane; at -30 - 20 ℃; diastereoselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1021/ja9055245

Reference yield:

: 34234-44-1
methyl 2,3,4-tri-O-benzoylglucopyranoside

: 1241376-04-4
3,4,6-tri-O-acetyl-2-azido-2-deoxy-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate

: methyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

: methyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Guidance literature:: With trifluoromethanesulfonyloxy(triphenylphosphine)gold(I); trifluorormethanesulfonic acid; In dichloromethane; at 20 ℃; for 3h; optical yield given as %de; Molecular sieve;
DOI:10.1002/anie.201103409