1-((S)-(S)-2-Allyloxy-3,3-dichloro-3-fluoro-propane-1-sulfinyl)-4-methyl-benzene

Base Information

Chemical Name:1-((S)-(S)-2-Allyloxy-3,3-dichloro-3-fluoro-propane-1-sulfinyl)-4-methyl-benzene
CAS No.:133343-55-2
Molecular Formula:C₁₃H₁₅Cl₂FO₂S
Molecular Weight:325.231
Hs Code.:

Synonyms:1-((S)-(S)-2-Allyloxy-3,3-dichloro-3-fluoro-propane-1-sulfinyl)-4-methyl-benzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-((S)-(S)-2-Allyloxy-3,3-dichloro-3-fluoro-propane-1-sulfinyl)-4-methyl-benzene

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Technology Process of 1-((S)-(S)-2-Allyloxy-3,3-dichloro-3-fluoro-propane-1-sulfinyl)-4-methyl-benzene

There total 2 articles about 1-((S)-(S)-2-Allyloxy-3,3-dichloro-3-fluoro-propane-1-sulfinyl)-4-methyl-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 133343-51-8
(S)-1,1-Dichloro-1-fluoro-3-((S)-toluene-4-sulfinyl)-propan-2-ol

: 106-95-6
allyl bromide

: 133343-55-2
1-((S)-(S)-2-Allyloxy-3,3-dichloro-3-fluoro-propane-1-sulfinyl)-4-methyl-benzene

Guidance literature:: With sodium hydroxide; trioctylethyl-ammonium bromide; In dichloromethane; Ambient temperature;

Reference yield:

: 5056-07-5
(S)-methyl p-tolyl sulfoxide

: 133343-55-2
1-((S)-(S)-2-Allyloxy-3,3-dichloro-3-fluoro-propane-1-sulfinyl)-4-methyl-benzene

Guidance literature:: Multi-step reaction with 2 steps

2: 88 percent / ethyltrioctylammonium bromide, 10 N aq. NaOH / CH₂Cl₂ / Ambient temperature

With sodium hydroxide; trioctylethyl-ammonium bromide; In dichloromethane;

Reference yield:

: 133343-55-2
1-((S)-(S)-2-Allyloxy-3,3-dichloro-3-fluoro-propane-1-sulfinyl)-4-methyl-benzene

: (2S,3R,4R,S_S)-3-Chloro-3-fluoro-4-methyl-2-<(4-methylphenylsulfinyl)methyl>tetrahydrofuran

: (2S,3R,4S,S_S)-3-Chloro-3-fluoro-4-methyl-2-<(4-methylphenylsulfinyl)methyl>tetrahydrofuran

: (2S,3S,4R,S_S)-3-Chloro-3-fluoro-4-methyl-2-<(4-methylphenylsulfinyl)methyl>tetrahydrofuran

: (2S,3S,4S,S_S)-3-Chloro-3-fluoro-4-methyl-2-<(4-methylphenylsulfinyl)methyl>tetrahydrofuran

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 75 ℃; for 8h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/S0040-4020(01)85741-0