[(1S,3S)-3-hydroxymethyl-6,6-dimethyl-2-methylenecyclohexyl]methanol O-tert-butyldiphenylsilyl ether

Base Information

• Chemical Name: [(1S,3S)-3-hydroxymethyl-6,6-dimethyl-2-methylenecyclohexyl]methanol O-tert-butyldiphenylsilyl ether
• CAS No.: 1187953-99-6
• Molecular Formula: C₂₇H₃₈O₂Si
• Molecular Weight: 422.683

Synonyms:[(1S,3S)-3-hydroxymethyl-6,6-dimethyl-2-methylenecyclohexyl]methanol O-tert-butyldiphenylsilyl ether

Chemical Property of [(1S,3S)-3-hydroxymethyl-6,6-dimethyl-2-methylenecyclohexyl]methanol O-tert-butyldiphenylsilyl ether

Chemical Property:

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Technology Process of [(1S,3S)-3-hydroxymethyl-6,6-dimethyl-2-methylenecyclohexyl]methanol O-tert-butyldiphenylsilyl ether

There total 1 articles about [(1S,3S)-3-hydroxymethyl-6,6-dimethyl-2-methylenecyclohexyl]methanol O-tert-butyldiphenylsilyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1,3,5-Trioxan (110-88-3) + C26H36OSi (1187954-23-9) → [(1S,3S)-3-hydroxymethyl-6,6-dimethyl-2-methylenecyclohexyl]methanol O-tert-butyldiphenylsilyl ether (1187953-99-6)

Guidance literature:

1,3,5-Trioxan; With (1,1';3',1''-terphenyl)-2'-ol; trimethylaluminum; In dichloromethane; toluene; at 0 ℃; for 1h; Inert atmosphere;

C₂₆H₃₆OSi; In dichloromethane; toluene; at 0 ℃; for 2h; diastereoselective reaction; Inert atmosphere;

DOI:10.1021/jo9014936

Reference yield: 88.0%

ortho-nitrophenyl selenocyanate (51694-22-5) + [(1S,3S)-3-hydroxymethyl-6,6-dimethyl-2-methylenecyclohexyl]methanol O-tert-butyldiphenylsilyl ether (1187953-99-6) → C33H41NO3SeSi (1187954-24-0)

Guidance literature:

With tributylphosphine; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/jo9014936

Reference yield: 85.0%

[(1S,3S)-3-hydroxymethyl-6,6-dimethyl-2-methylenecyclohexyl]methanol O-tert-butyldiphenylsilyl ether (1187953-99-6) + acetic anhydride (108-24-7) → C29H40O3Si (1187954-25-1)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1021/jo9014936

upstream raw materials:

1,3,5-Trioxan

C₂₆H₃₆OSi

Downstream raw materials:

C₃₃H₄₁NO₃SeSi

C₂₉H₄₀O₃Si

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