(E)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

Base Information

Chemical Name:(E)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime
CAS No.:1438263-49-0
Molecular Formula:C₄₃H₄₉NO₆Si
Molecular Weight:703.951
Hs Code.:

Synonyms:(E)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

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Chemical Property of (E)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

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Technology Process of (E)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

There total 5 articles about (E)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3,4,6-tri-O-benzyl-l-sorbose

: 103587-51-5
O-(tert-butyl)diphenylsilylhydroxylamine

: 1438263-49-0
(E)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

: (Z)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

Guidance literature:: 3,4,6-tri-O-benzyl-l-sorbose; With magnesium sulfate; In toluene; for 0.333333h; Inert atmosphere;

O-(tert-butyl)diphenylsilylhydroxylamine; With pyridinium p-toluenesulfonate; In toluene; for 48h; Overall yield = 70 %; Overall yield = 4.98 g; Reflux; Inert atmosphere;
DOI:10.1016/j.carres.2013.03.017

Reference yield:

: 1438263-43-4
3-O-benzyl-1,2-4,6-di-O-isopropylidene l-sorbose

: 1438263-49-0
(E)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

: (Z)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

Guidance literature:: Multi-step reaction with 4 steps

1.1: acetic acid / water / 20 °C / Inert atmosphere

2.1: sodium hydride / tetrahydrofuran; mineral oil / 20 °C / Inert atmosphere

3.1: acetic acid / water / 50 °C / Inert atmosphere

4.1: magnesium sulfate / toluene / 0.33 h / Inert atmosphere

4.2: 48 h / Reflux; Inert atmosphere

With sodium hydride; magnesium sulfate; acetic acid; In tetrahydrofuran; water; toluene; mineral oil;
DOI:10.1016/j.carres.2013.03.017

Reference yield:

: 1438263-44-5
3-O-benzyl-1,2-O-isopropylidene l-sorbose

: 1438263-49-0
(E)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

: (Z)-3,4,6-tri-O-benzyl-l-xylo-Hex-2-ulose tertiobutyldiphenylsilyloxime

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / tetrahydrofuran; mineral oil / 20 °C / Inert atmosphere

2.1: acetic acid / water / 50 °C / Inert atmosphere

3.1: magnesium sulfate / toluene / 0.33 h / Inert atmosphere

3.2: 48 h / Reflux; Inert atmosphere

With sodium hydride; magnesium sulfate; acetic acid; In tetrahydrofuran; water; toluene; mineral oil;
DOI:10.1016/j.carres.2013.03.017