((2,6-[CH(CH₃)2]2C₆H₃)NC(CH₃)CHC(O)=CPh₂C(CH₃)N(2,6-[CH(CH₃)2]2C₆H₃))Ti=NC₆H₃-2,6-[CH(CH₃)2]2(OTf)

Base Information

• Chemical Name: ((2,6-[CH(CH₃)2]2C₆H₃)NC(CH₃)CHC(O)=CPh₂C(CH₃)N(2,6-[CH(CH₃)2]2C₆H₃))Ti=NC₆H₃-2,6-[CH(CH₃)2]2(OTf)
• CAS No.: 636563-89-8
• Molecular Formula: C₅₆H₆₈F₃N₃O₄STi
• Molecular Weight: 984.115
• Mol file: 636563-89-8.mol

Synonyms:((2,6-[CH(CH₃)2]2C₆H₃)NC(CH₃)CHC(O)=CPh₂C(CH₃)N(2,6-[CH(CH₃)2]2C₆H₃))Ti=NC₆H₃-2,6-[CH(CH₃)2]2(OTf)

Chemical Property of ((2,6-[CH(CH₃)2]2C₆H₃)NC(CH₃)CHC(O)=CPh₂C(CH₃)N(2,6-[CH(CH₃)2]2C₆H₃))Ti=NC₆H₃-2,6-[CH(CH₃)2]2(OTf)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((2,6-[CH(CH₃)2]2C₆H₃)NC(CH₃)CHC(O)=CPh₂C(CH₃)N(2,6-[CH(CH₃)2]2C₆H₃))Ti=NC₆H₃-2,6-[CH(CH₃)2]2(OTf)

There total 1 articles about ((2,6-[CH(CH₃)2]2C₆H₃)NC(CH₃)CHC(O)=CPh₂C(CH₃)N(2,6-[CH(CH₃)2]2C₆H₃))Ti=NC₆H₃-2,6-[CH(CH₃)2]2(OTf) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

((2,6-[CH(CH3)2]2C6H3)NC(CH3)CHC(CH3)N(2,6-[CH(CH3)2]2C6H3))Ti=NC6H3-2,6-[CH(CH3)2]2(OTf) (623924-17-4) + diphenyl ketene (525-06-4) → ((2,6-[CH(CH3)2]2C6H3)NC(CH3)CHC(O)=CPh2C(CH3)N(2,6-[CH(CH3)2]2C6H3))Ti=NC6H3-2,6-[CH(CH3)2]2(OTf) (636563-89-8)

Guidance literature:

In diethyl ether; to soln. Ti complex in Et2O at -35°C soln. Ph2CCO in Et2O was added and stirred for 50 min; ppt. was filtered, washed with pentane, and recrystd. from THF layered with pentane at -35°C; elem. anal.;

DOI:10.1021/ic034853e

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + ((2,6-[CH(CH3)2]2C6H3)NC(CH3)CHC(O)=CPh2C(CH3)N(2,6-[CH(CH3)2]2C6H3))Ti=NC6H3-2,6-[CH(CH3)2]2(OTf) (636563-89-8) → ((2,6-[CH(CH3)2]2C6H3)NC(CH3)CHC(O)=CPh2C(CH3)N(2,6-[CH(CH3)2]2C6H3))Ti=NC6H3-2,6-[CH(CH3)2]2(OTf)*2THF

Guidance literature:

In tetrahydrofuran; pentane;

DOI:10.1021/ic034853e

upstream raw materials:

((2,6-[CH(CH₃)2]2C₆H₃)NC(CH₃)CHC(CH₃)N(2,6-[CH(CH₃)2]2C₆H₃))Ti=NC₆H₃-2,6-[CH(CH₃)2]2(OTf)

diphenyl ketene