1,4-Benzodioxan-6,7-diol

Base Information

Chemical Name:1,4-Benzodioxan-6,7-diol
CAS No.:90111-35-6
Molecular Formula:C8H8 O4
Molecular Weight:168.1467
Hs Code.:2932999099
DSSTox Substance ID:DTXSID20550032
Nikkaji Number:J2.093.025J
Wikidata:Q82429240
Mol file:90111-35-6.mol

Synonyms:1,4-BENZODIOXAN-6,7-DIOL;90111-35-6;2,3-Dihydrobenzo[b][1,4]dioxine-6,7-diol;2,3-dihydro-1,4-benzodioxine-6,7-diol;SCHEMBL21489522;DTXSID20550032;AKOS006292069;1,4-Benzodioxin-6,7-diol,2,3-dihydro-;(2,2-BIPYRIDINE)DICHLOROPLATINUM(II)

Suppliers and Price of 1,4-Benzodioxan-6,7-diol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2,3-Dihydro-1,4-benzodioxin-6,7-diol
10mg
$ 75.00

Matrix Scientific
1,4-Benzodioxan-6,7-diol 98%
100mg
$ 90.00

American Custom Chemicals Corporation
1,4-BENZODIOXAN-6,7-DIOL 95.00%
100MG
$ 675.68

AK Scientific
1,4-Benzodioxan-6,7-diol
100mg
$ 171.00

Total 15 raw suppliers

Chemical Property of 1,4-Benzodioxan-6,7-diol

Chemical Property:

Vapor Pressure:5.94E-06mmHg at 25°C
Boiling Point:368.6 ºC at 760 mmHg
Flash Point:176.7 ºC
PSA：58.92000
Density:1.459 g/cm³
LogP:0.86900
XLogP3:0.9
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:168.04225873
Heavy Atom Count:12
Complexity:143

Purity/Quality:

98%Min ^*data from raw suppliers

2,3-Dihydro-1,4-benzodioxin-6,7-diol ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1COC2=C(O1)C=C(C(=C2)O)O

Technology Process of 1,4-Benzodioxan-6,7-diol

There total 5 articles about 1,4-Benzodioxan-6,7-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 90050-37-6
2,3-dihydrobenzo[1,4]dioxin-6,7-dione

: 90111-35-6
2,3-dihydrobenzo[1,4]dioxin-6,7-diol

Guidance literature:: With sodium dithionite; In water;
DOI:10.1016/j.tet.2004.07.017

Reference yield:

: 782471-87-8
formic acid 2,3-dihydro-benzo[1,4]dioxin-6-yl ester

: 90111-35-6
2,3-dihydrobenzo[1,4]dioxin-6,7-diol

Guidance literature:: Multi-step reaction with 3 steps

1: 73 percent / KOH / methanol / 0.75 h / 20 °C

2: 71 percent / KH₂PO₄; NO(KSO₃)2 / methanol; H₂O / 1.42 h / Cooling

3: 75 percent / Na₂S₂O₄ / H₂O

With potassium hydroxide; potassium dihydrogenphosphate; sodium dithionite; potassium nitrososulfonate; In methanol; water;
DOI:10.1016/j.tet.2004.07.017

Reference yield:

: 10288-72-9
dihydrobenzo[1,4]dioxin-6-ol

: 90111-35-6
2,3-dihydrobenzo[1,4]dioxin-6,7-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / KH₂PO₄; NO(KSO₃)2 / methanol; H₂O / 1.42 h / Cooling

2: 75 percent / Na₂S₂O₄ / H₂O

With potassium dihydrogenphosphate; sodium dithionite; potassium nitrososulfonate; In methanol; water;
DOI:10.1016/j.tet.2004.07.017