(α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanal

Base Information

Chemical Name:(α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanal
CAS No.:843644-68-8
Molecular Formula:C₂₄H₃₃BrO₄Si
Molecular Weight:493.513
Hs Code.:

Synonyms:(α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanal

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Technology Process of (α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanal

There total 9 articles about (α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 843644-66-6
(α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanol

: 843644-68-8
(α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanal

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; diisopropylamine; In dichloromethane; at -70 - 20 ℃; for 1.16667h;
DOI:10.1039/b414213f

Reference yield:

: 843644-58-6
5'-t-butyldimethylsilyloxy-2'-hydroxyacetophenone

: 843644-68-8
(α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanal

Guidance literature:: Multi-step reaction with 6 steps

1: Br₂

2: LiAlH₄

With lithium aluminium tetrahydride; bromine; 6: Swern oxidation;
DOI:10.1071/CH03286

Reference yield:

: 714962-11-5
2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxyacetophenone

: 843644-68-8
(α'R,2S)-2-(2'-benzyloxy-3'-bromo-5'-t-butyldimethylsilyloxy-α'-methylbenzyloxy)propanal

Guidance literature:: Multi-step reaction with 4 steps

1: LiAlH₄

With lithium aluminium tetrahydride; 4: Swern oxidation;
DOI:10.1071/CH03286