O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride

Base Information

Chemical Name:O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride
CAS No.:151072-59-2
Molecular Formula:C₄₂H₃₈Cl₂O₁₃
Molecular Weight:821.662
Hs Code.:

Synonyms:O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride

Suppliers and Price of O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride

There total 9 articles about O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 151072-58-1
Ethyl O-(2-O-benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-1-thio-α-D-glucopyranoside

: 151072-59-2
O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride

Guidance literature:: With chlorine; In tetrachloromethane; dichloromethane; chloroform; at 0 ℃; for 0.0833333h;
DOI:10.1016/0008-6215(93)80061-I

Reference yield:

: 151123-93-2
Ethyl 2-O-benzoyl-4,6-O-benzylidene-1-thio-α-D-glucopyranoside

: 151072-59-2
O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / pyridine / CH₂Cl₂ / 0.33 h / 0 °C

2: 84 percent / Cl₂ / CCl₄; CHCl₃ / 0.08 h / 0 °C

3: 90 percent / silver triflate, DTBMP, molecular sieves 4A / CH₂Cl₂; toluene; nitromethane / 1 h / Ambient temperature

4: 82 percent / Cl₂ / CHCl₃; CCl₄; CH₂Cl₂ / 0.08 h / 0 °C

With pyridine; 2,6-di-tert-butyl-4-methylpyridine; 4 A molecular sieve; silver trifluoromethanesulfonate; chlorine; In tetrachloromethane; nitromethane; dichloromethane; chloroform; toluene;
DOI:10.1016/0008-6215(93)80061-I

Reference yield:

: 151123-92-1
Ethyl 4,6-O-benzylidene-1-thio-α-D-glucopyranoside

: 151072-59-2
O-(2-O-Benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranosyl chloride

Guidance literature:: Multi-step reaction with 5 steps

1: 83 percent / NEt₃ / CH₂Cl₂ / 2 h / Ambient temperature

2: 93 percent / pyridine / CH₂Cl₂ / 0.33 h / 0 °C

3: 84 percent / Cl₂ / CCl₄; CHCl₃ / 0.08 h / 0 °C

4: 90 percent / silver triflate, DTBMP, molecular sieves 4A / CH₂Cl₂; toluene; nitromethane / 1 h / Ambient temperature

5: 82 percent / Cl₂ / CHCl₃; CCl₄; CH₂Cl₂ / 0.08 h / 0 °C

With pyridine; 2,6-di-tert-butyl-4-methylpyridine; 4 A molecular sieve; silver trifluoromethanesulfonate; chlorine; triethylamine; In tetrachloromethane; nitromethane; dichloromethane; chloroform; toluene;
DOI:10.1016/0008-6215(93)80061-I