N-tosyl-2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-(1,3)-dithiolo[4,5-c]pyrrole

Base Information

Chemical Name:N-tosyl-2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-(1,3)-dithiolo[4,5-c]pyrrole
CAS No.:960365-01-9
Molecular Formula:C₂₃H₂₇NO₂S₇
Molecular Weight:573.935
Hs Code.:

Synonyms:N-tosyl-2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-(1,3)-dithiolo[4,5-c]pyrrole

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Chemical Property of N-tosyl-2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-(1,3)-dithiolo[4,5-c]pyrrole

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Technology Process of N-tosyl-2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-(1,3)-dithiolo[4,5-c]pyrrole

There total 5 articles about N-tosyl-2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-(1,3)-dithiolo[4,5-c]pyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 122891-19-4
4,5-bis(2-butylsulfanyl)-1,3-dithiole-2-thione

: 250687-28-6
5-tosyl-[1,3]dithiolo[4,5-c]pyrrol-2-one

: 960365-01-9
N-tosyl-2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-(1,3)-dithiolo[4,5-c]pyrrole

Guidance literature:: With triethyl phosphite; at 130 ℃; for 1.46667h; Inert atmosphere;
DOI:10.1002/chem.201302461

Reference yield:

: 250687-26-4
4,6-dihydro-N-tosyl-(1,3)-dithiolo[4,5-c]pyrrole-2-one

: 960365-01-9
N-tosyl-2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-(1,3)-dithiolo[4,5-c]pyrrole

Guidance literature:: Multi-step reaction with 2 steps

1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / chlorobenzene / 4 h / Reflux; Inert atmosphere

2: triethyl phosphite / Inert atmosphere; Heating

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; triethyl phosphite; In chlorobenzene;
DOI:10.3762/bjoc.11.125

Reference yield:

: 7396-41-0
4,5-bis(methoxycarbonyl)-1,3-dithiole-2-thione

: 960365-01-9
N-tosyl-2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-(1,3)-dithiolo[4,5-c]pyrrole

Guidance literature:: Multi-step reaction with 6 steps

1: lithium bromide; sodium tetrahydroborate / tetrahydrofuran; methanol / -10 - 20 °C / Inert atmosphere

2: phosphorus tribromide / tetrahydrofuran / 20 h / 0 - 20 °C / Inert atmosphere

3: acetonitrile; N,N-dimethyl-formamide / 0.25 h / 80 °C / Inert atmosphere

4: acetic acid; mercury(II) diacetate / chloroform / 24 h / 20 °C / Irradiation

5: 2,3-dicyano-5,6-dichloro-p-benzoquinone / chlorobenzene / 4 h / Reflux; Inert atmosphere

6: triethyl phosphite / Inert atmosphere; Heating

With sodium tetrahydroborate; mercury(II) diacetate; phosphorus tribromide; acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium bromide; triethyl phosphite; In tetrahydrofuran; methanol; chloroform; N,N-dimethyl-formamide; chlorobenzene; acetonitrile;
DOI:10.3762/bjoc.11.125