C₃₃H₄₆O₇Si

Base Information

Chemical Name:C₃₃H₄₆O₇Si
CAS No.:1419778-46-3
Molecular Formula:C₃₃H₄₆O₇Si
Molecular Weight:582.81
Hs Code.:

C<sub>33</sub>H<sub>46</sub>O<sub>7</sub>Si

Synonyms:C₃₃H₄₆O₇Si

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Chemical Property of C₃₃H₄₆O₇Si

Chemical Property:

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Technology Process of C₃₃H₄₆O₇Si

There total 28 articles about C₃₃H₄₆O₇Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 1419778-00-9
C₂₃H₂₄O₅

: 71171-66-9,92775-37-6,116839-04-4,72150-39-1
(3R)-3-(tert-butyldimethylsilyloxy)butanal

: 1419778-46-3
C₃₃H₄₆O₇Si

Guidance literature:: C₂₃H₂₄O₅; With (+)-β-chlorodiisopinocampheylborane; triethylamine; In diethyl ether; at -78 - 0 ℃; for 1h;

(3R)-3-(tert-butyldimethylsilyloxy)butanal; In diethyl ether; at -78 ℃; for 2h;
DOI:10.1021/ol303482k

Reference yield:

: 1419778-00-9
C₂₃H₂₄O₅

: 71171-66-9,92775-37-6,116839-04-4,72150-39-1
(3R)-3-(tert-butyldimethylsilyloxy)butanal

: 1419778-46-3
C₃₃H₄₆O₇Si

: 1419778-52-1
C₃₃H₄₆O₇Si

Guidance literature:: C₂₃H₂₄O₅; With (-)-diisopinocampheyl chloride; triethylamine; In diethyl ether; at -78 - 0 ℃; for 1h;

(3R)-3-(tert-butyldimethylsilyloxy)butanal; In diethyl ether; at -78 ℃; for 2h; Overall yield = 31 %; Overall yield = 34 mg;
DOI:10.1021/ol303482k

Reference yield:

: 480-34-2
eugenin

: 1419778-46-3
C₃₃H₄₆O₇Si

Guidance literature:: Multi-step reaction with 13 steps

1.1: potassium carbonate; tetra-(n-butyl)ammonium iodide / acetone / 24 h / Reflux

2.1: 2 h / 200 °C

3.1: potassium carbonate; tetra-(n-butyl)ammonium iodide / acetone / 24 h / Reflux

4.1: (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) / tetrahydrofuran / 3 h / Reflux

5.1: 2,6-dimethylpyridine; osmium(VIII) oxide; sodium periodate / 1,4-dioxane; water; tert-butyl alcohol / 0.5 h

6.1: sodium tetrahydroborate; methanol / tetrahydrofuran / 0.08 h / 0 °C

7.1: phosphorus tribromide / tetrahydrofuran; dichloromethane / 4.5 h / 0 °C

8.1: sodium hexamethyldisilazane / tetrahydrofuran / 1 h / -78 °C

8.2: 0.5 h / -78 °C

9.1: methanol; lithium borohydride / tetrahydrofuran; diethyl ether / 5 h

10.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 3 h / 20 °C

11.1: lithium chloride / tetrahydrofuran; diethyl ether / 0.5 h / -78 °C

12.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 3 h / 20 °C

13.1: triethylamine; (+)-β-chlorodiisopinocampheylborane / diethyl ether / 1 h / -78 - 0 °C

13.2: 2 h / -78 °C

With 2,6-dimethylpyridine; methanol; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; lithium borohydride; (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); (+)-β-chlorodiisopinocampheylborane; sodium hexamethyldisilazane; phosphorus tribromide; tetra-(n-butyl)ammonium iodide; potassium carbonate; triethylamine; lithium chloride; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; water; dimethyl sulfoxide; acetone; tert-butyl alcohol;
DOI:10.1021/ol303482k