{difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium

Base Information

• Chemical Name: {difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium
• CAS No.: 53335-25-4
• Molecular Formula: C₁₃H₂₂BF₂N₄O₂Rh
• Molecular Weight: 418.057
• Mol file: 53335-25-4.mol

Synonyms:{difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium

Chemical Property of {difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium

There total 1 articles about {difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{difluoro{N,N'-bis(3-butanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium + benzylchloro{difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium (99355-15-4) → {difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium (53335-25-4) + benzylchloro{difluoro{N,N'-bis(3-butanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium

Guidance literature:

In [D₃]acetonitrile; at 28.5°C in CD3CN soln.; monitored by NMR; Kinetics;

DOI:10.1021/om00133a007

Reference yield: 81.0%

{difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium (53335-25-4) + 1-iodo-2-methyl-2-phenylpropane (19479-63-1) → trans-(neophyl)iodo{2,2'-{1,3-propanediylbis(nitrilo)}bis{3-pentanone oximato}}rhodium(III)

Guidance literature:

With water; In acetonitrile; under N2, soln. of Rh complex in MeCN treated with 2-fold excess of PhMe2CCH2I, stirred and heated under reflux for 40 min; evapd., recrystd. from CH2Cl2 by addn. of mixt. of THF and cyclohexane, crystals washed with ether; elem. anal.;

Reference yield: 76.0%

1-bromocyclohexane (108-85-0) + {difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium (53335-25-4) → trans-dibromo{difluoro{2,2'-{1,3-propanediylbis(nitrilo)}bis{3-pentanone oximato}}borato}rhodium(III) + trans-(cyclohexyl)bromo{difluoro{2,2'-{1,3-propanediylbis(nitrilo)}bis{3-pentanone oximato}}borato}rhodium(III) (99355-25-6)

Guidance literature:

In acetonitrile; under N2, Rh(I) reagent treated with large excess of c-C6H11Br in MeCN at reflux for 3 h; sepd. by chromy. (SiO2, 30% MeCN/CH2Cl2), recrystd. from CH2Cl2/EtOH; elem. anal.; Kinetics;

upstream raw materials:

benzylchloro{difluoro{N,N'-bis(3-pentanon-2-ylidene)-1,3-diaminopropanedioximato}borato}rhodium

Downstream raw materials:

cyclohexene

trans-(cyclohexyl)bromo{difluoro{2,2'-{1,3-propanediylbis(nitrilo)}bis{3-pentanone oximato}}borato}rhodium(III)

ethene

propene

Refernces