Bis(2-methoxyphenyl)chlorophosphine

Base Information

Chemical Name:Bis(2-methoxyphenyl)chlorophosphine
CAS No.:263369-88-6
Molecular Formula:C14H14 Cl O2 P
Molecular Weight:280.691
Hs Code.:
European Community (EC) Number:679-144-7
Wikidata:Q106902843
Mol file:263369-88-6.mol

Synonyms:263369-88-6;Bis(2-methoxyphenyl)chlorophosphine;Chlorobis(2-methoxyphenyl)phosphine;Phosphinous chloride, P,P-bis(2-methoxyphenyl)-;BIS(2-METHOXYPHENYL)CHLORPHOSPHINE;chloro-bis(2-methoxyphenyl)phosphane;CHLOROBIS(2-METHOXYPHENYL)PHOSPHANE;SCHEMBL889796;PEKLJSZEUFVLKO-UHFFFAOYSA-N;MFCD08064037;AKOS037646246;AS-67574;Bis(2-methoxyphenyl)chlorophosphine, 95%

Suppliers and Price of Bis(2-methoxyphenyl)chlorophosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Bis(2-methoxyphenyl)chlorophosphine 95%
1g
$ 124.00

American Custom Chemicals Corporation
BIS-(2-METHOXYPHENYL)CHLOROPHOSPHINE 95.00%
1G
$ 210.00

Alfa Aesar
Chlorobis(2-methoxyphenyl)phosphine, 98+%
5g
$ 339.00

Alfa Aesar
Chlorobis(2-methoxyphenyl)phosphine, 98+%
1g
$ 110.00

Total 21 raw suppliers

Chemical Property of Bis(2-methoxyphenyl)chlorophosphine

Chemical Property:

Vapor Pressure:1.66E-06mmHg at 25°C
Melting Point:111-114°C
Boiling Point:408.4°Cat760mmHg
Flash Point:200.8°C
PSA：32.05000
Density:g/cm³
LogP:3.29030
Sensitive.:Moisture Sensitive
Water Solubility.:Reacts with water.
XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:280.0419944
Heavy Atom Count:18
Complexity:228

Purity/Quality:

98% ^*data from raw suppliers

Bis(2-methoxyphenyl)chlorophosphine 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C
Statements: 14-34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=CC=C1P(C2=CC=CC=C2OC)Cl
Uses Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

Technology Process of Bis(2-methoxyphenyl)chlorophosphine

There total 8 articles about Bis(2-methoxyphenyl)chlorophosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: (2-MeO-C₆H₄)2P-N(i-Pr)2

: 263369-88-6
di-o-anisylphosphinyl chloride

Guidance literature:: With hydrogenchloride; In diethyl ether; for 0.5h; under 206.865 Torr; Inert atmosphere;

Reference yield: 89.0%

: 103223-33-2
N,N-diethylamino-bis-(o-methoxyphenyl)phosphine

: 263369-88-6
di-o-anisylphosphinyl chloride

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; diethyl ether; at -78 ℃; for 1h; Inert atmosphere; Schlenk technique;
DOI:10.1016/j.jorganchem.2019.06.012

Reference yield: 27.5%

: 1069-08-5
diethylphosphoramidous dichloride

: 578-57-4
2-bromoanisole

: 263369-88-6
di-o-anisylphosphinyl chloride

Guidance literature:: 2-bromoanisole; With magnesium; In diethyl ether; Inert atmosphere; Reflux;

diethylphosphoramidous dichloride; In diethyl ether; Inert atmosphere;
DOI:10.1039/b913302j