(S)-(E)-2-(3-hydroxybut-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate

Base Information

• Chemical Name: (S)-(E)-2-(3-hydroxybut-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate
• CAS No.: 1005143-42-9
• Molecular Formula: C₃₂H₂₈O₅
• Molecular Weight: 492.571
• Mol file: 1005143-42-9.mol

Synonyms:(S)-(E)-2-(3-hydroxybut-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate

Chemical Property of (S)-(E)-2-(3-hydroxybut-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate

Chemical Property:

Purity/Quality:

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Technology Process of (S)-(E)-2-(3-hydroxybut-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate

There total 1 articles about (S)-(E)-2-(3-hydroxybut-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

2-iodo-5-phenethyl-1,3-phenylene dibenzoate (1005143-38-3) + (S)-(E)-4-(tributylstannyl)but-3-en-2-ol → (S)-(E)-2-(3-hydroxybut-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate (1005143-42-9)

Guidance literature:

With copper(l) iodide; tri-tert-butyl phosphine; cesium fluoride; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In toluene; at 80 ℃; for 5h;

DOI:10.1021/ol702692q

Reference yield: 98.0%

(S)-(E)-2-(3-hydroxybut-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate (1005143-42-9) + 5-methylhex-5-enoic acid (55170-74-6) → (S)-(E)-2-(3-(5-methylhex-5-enyloxy)but-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate (1005143-43-0)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 16h;

DOI:10.1021/ol702692q

upstream raw materials:

2-iodo-5-phenethyl-1,3-phenylene dibenzoate

Downstream raw materials:

(S)-(E)-2-(3-(5-methylhex-5-enyloxy)but-1-enyl)-5-phenethyl-1,3-phenylene dibenzoate