2-(6-(2-iodophenyl)-3-(phenylsulfonyl)hex-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-(6-(2-iodophenyl)-3-(phenylsulfonyl)hex-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:1424999-66-5
Molecular Formula:C₂₄H₃₀BIO₄S
Molecular Weight:552.281
Hs Code.:

Synonyms:2-(6-(2-iodophenyl)-3-(phenylsulfonyl)hex-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Chemical Property of 2-(6-(2-iodophenyl)-3-(phenylsulfonyl)hex-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Technology Process of 2-(6-(2-iodophenyl)-3-(phenylsulfonyl)hex-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 6 articles about 2-(6-(2-iodophenyl)-3-(phenylsulfonyl)hex-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 1424999-26-7
4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

: 115860-48-5
1-iodo-3-(2-iodophenyl)propane

: 1424999-66-5
2-(6-(2-iodophenyl)-3-(phenylsulfonyl)hex-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

1-iodo-3-(2-iodophenyl)propane; In tetrahydrofuran; at 20 ℃; for 3h;
DOI:10.1039/c3cc00030c

Reference yield: 65.0%

: 1424999-26-7
4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

: 3-(2-iodophenyl)propyl trifluoromethanesulfonate

: 1424999-66-5
2-(6-(2-iodophenyl)-3-(phenylsulfonyl)hex-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

3-(2-iodophenyl)propyl trifluoromethanesulfonate; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1021/acs.joc.5b01253

Reference yield:

: 1424999-30-3
2-(2-iodo-1-(phenylsulfonyl)propan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1424999-66-5
2-(6-(2-iodophenyl)-3-(phenylsulfonyl)hex-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine / dichloromethane / 96 h / Reflux

2.1: lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 °C

2.2: 3 h / 20 °C

With triethylamine; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1039/c3cc00030c