(S,S)-(-)-1-r,2-c,5-t-triphenylphospholane

Base Information

Chemical Name:(S,S)-(-)-1-r,2-c,5-t-triphenylphospholane
CAS No.:138258-77-2
Molecular Formula:C₂₂H₂₁P
Molecular Weight:316.382
Hs Code.:

Synonyms:(S,S)-(-)-1-r,2-c,5-t-triphenylphospholane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S,S)-(-)-1-r,2-c,5-t-triphenylphospholane

Chemical Property:

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Technology Process of (S,S)-(-)-1-r,2-c,5-t-triphenylphospholane

There total 15 articles about (S,S)-(-)-1-r,2-c,5-t-triphenylphospholane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 474093-54-4
(2S,5S)-(-)-1-r-oxo-1,2-c,5-triphenyl phospholane

: 138258-77-2
(S,S)-(-)-1-r,2-c,5-t-triphenylphospholane

Guidance literature:: With lithium aluminium tetrahydride; methyl iodide; In 1,2-dimethoxyethane;
DOI:10.1039/b603659g

Reference yield: 70.0%

: C₂₂H₂₄BP

: 138258-77-2
(S,S)-(-)-1-r,2-c,5-t-triphenylphospholane

Guidance literature:: C₂₂H₂₄BP; With tetrafluoroboric acid dimethylether; In dichloromethane; at 0 - 20 ℃;

With sodium hydrogencarbonate; In dichloromethane; at 0 ℃; Inert atmosphere;
DOI:10.1002/cctc.201402687

Reference yield:

: 886-65-7,538-81-8
trans,trans-1,4-Diphenyl-1,3-butadiene

: 138258-77-2
(S,S)-(-)-1-r,2-c,5-t-triphenylphospholane

Guidance literature:: Multi-step reaction with 8 steps

1.1: AlCl₃ / CH₂Cl₂ / 16 h / 0 °C

2.1: 16.5 g / NaHCO₃; EDTA / CH₂Cl₂ / 4 h / 0 °C

3.1: 92 percent / hydrogen / 10 percent Pd/C / methanol / 16 h / 37503 Torr

4.1: 95 percent / NaOMe / methanol / 1.25 h / 20 °C

5.1: 1.18 g / HCl / H₂O; ethanol / 16 h / 20 °C

6.1: 95 percent / oxalyl chloride / tetrahydrofuran / 2 h

7.1: CuBr-dimethylsulfide complex / tetrahydrofuran; diethyl ether / 1.15 h / -60 °C

7.2: 1.70 g / NH₄Cl; ammonia / tetrahydrofuran; diethyl ether; H₂O / -60 - 20 °C

8.1: methyl trifluoromethanesulfonate / 1,2-dimethoxy-ethane / 2 h / 20 °C

8.2: lithium aluminium hydride / 1,2-dimethoxy-ethane / 1.5 h / 20 °C

With hydrogenchloride; aluminium trichloride; oxalyl dichloride; copper(I) bromide dimethylsulfide complex; ethylenediaminetetraacetic acid; hydrogen; sodium methylate; sodium hydrogencarbonate; methyl trifluoromethanesulfonate; palladium on activated charcoal; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; diethyl ether; ethanol; dichloromethane; water; 1.1: McCormack cycloaddition;
DOI:10.1016/S0040-4020(02)00554-9