9ALPHA, 11ALPHA, 15S-TRIHYDROXY-PROSTA-5Z, 13E-DIEN-1-OIC ACID, 1,9-LACTONE

Base Information

• Chemical Name: 9ALPHA, 11ALPHA, 15S-TRIHYDROXY-PROSTA-5Z, 13E-DIEN-1-OIC ACID, 1,9-LACTONE
• CAS No.: 55314-48-2
• Molecular Formula: C₂₀H₃₂O₄
• Molecular Weight: 336.472
• Mol file: 55314-48-2.mol

Synonyms:Cyclopent[b]oxecin,prosta-5,13-dien-1-oic acid deriv.; PGF2a 1,9-lactone

Chemical Property of 9ALPHA, 11ALPHA, 15S-TRIHYDROXY-PROSTA-5Z, 13E-DIEN-1-OIC ACID, 1,9-LACTONE

Chemical Property:

• PSA: 66.76000
• LogP: 3.52280

Purity/Quality:

99% ^*data from raw suppliers

Prostaglandin F2α 1,9-lactone ≥99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: PGF2α 1,9-lactone is a lipid-soluble internal ester of PGF2α. It is resistant to hydrolysis by human plasma esterases even after incubation for 20 hours under physiological conditions. PGF2α 1,9-lactone exhibits little antifertility and vasoactivity compared to PGF2α.

Technology Process of 9ALPHA, 11ALPHA, 15S-TRIHYDROXY-PROSTA-5Z, 13E-DIEN-1-OIC ACID, 1,9-LACTONE

There total 3 articles about 9ALPHA, 11ALPHA, 15S-TRIHYDROXY-PROSTA-5Z, 13E-DIEN-1-OIC ACID, 1,9-LACTONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dinoprost (551-11-1) → PGF2α 1,9-lactone (55314-48-2)

Guidance literature:

Multi-step reaction with 2 steps

1: Ph₃P / benzene / 3.5 h / 35 °C

2: benzene / 18 h / Heating

With triphenylphosphine; In benzene;

DOI:10.1021/jm00362a001

Reference yield:

(Z)-7-[(1R,2R,3R,5S)-3,5-Dihydroxy-2-((E)-(S)-3-hydroxy-oct-1-enyl)-cyclopentyl]-hept-5-enethioic acid S-pyridin-2-yl ester (81340-03-6) → PGF2α 1,9-lactone (55314-48-2)

Guidance literature:

In benzene; for 18h; Yield given; Heating;

DOI:10.1021/jm00362a001

Reference yield:

→ PGF2α 1,9-lactone (55314-48-2)

Guidance literature:

PGF(2α), Pyridiniumsalz I, Dimethylpyridin, quart. Ammoniumsalz;

upstream raw materials:

(Z)-7-[(1R,2R,3R,5S)-3,5-Dihydroxy-2-((E)-(S)-3-hydroxy-oct-1-enyl)-cyclopentyl]-hept-5-enethioic acid S-pyridin-2-yl ester

dinoprost

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