N-<4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoyl>glycine ethyl ester

Base Information

Chemical Name:N-<4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoyl>glycine ethyl ester
CAS No.:171905-67-2
Molecular Formula:C₂₉H₃₅NO₉
Molecular Weight:541.598
Hs Code.:

Synonyms:N-<4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoyl>glycine ethyl ester

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Chemical Property of N-<4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoyl>glycine ethyl ester

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Technology Process of N-<4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoyl>glycine ethyl ester

There total 5 articles about N-<4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoyl>glycine ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 623-33-6
glycine ethyl ester hydrochloride

: 171905-66-1
4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoic acid

: 171905-67-2
N-<4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoyl>glycine ethyl ester

Guidance literature:: With 1-hydroxy-pyrrolidine-2,5-dione; triethylamine; dicyclohexyl-carbodiimide; In dichloromethane; for 4h; Ambient temperature;
DOI:10.1021/jm00026a004

Reference yield:

: 40501-40-4
methyl 2'-hydroxybiphenyl-4-carboxylate

: 171905-67-2
N-<4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoyl>glycine ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: BF₃*Et₂O / 1,2-dichloro-ethane / Ambient temperature

2: aq. LiOH / acetonitrile / Ambient temperature

3: 0.7 g / acetone, p-toluenesulfonic acid monohydrate / 0.75 h / Ambient temperature

4: 89 percent / Et₃N, N-hydroxysuccinimide, N,N'-dicyclohexylcarbodiimide / CH₂Cl₂ / 4 h / Ambient temperature

With lithium hydroxide; 1-hydroxy-pyrrolidine-2,5-dione; boron trifluoride diethyl etherate; toluene-4-sulfonic acid; triethylamine; dicyclohexyl-carbodiimide; acetone; In dichloromethane; 1,2-dichloro-ethane; acetonitrile;
DOI:10.1021/jm00026a004

Reference yield:

: 171905-43-4
4-<2-(α-D-mannopyranosyloxy)phenyl>benzoic acid

: 171905-67-2
N-<4-<2-<(2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl)oxy>phenyl>benzoyl>glycine ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 0.7 g / acetone, p-toluenesulfonic acid monohydrate / 0.75 h / Ambient temperature

2: 89 percent / Et₃N, N-hydroxysuccinimide, N,N'-dicyclohexylcarbodiimide / CH₂Cl₂ / 4 h / Ambient temperature

With 1-hydroxy-pyrrolidine-2,5-dione; toluene-4-sulfonic acid; triethylamine; dicyclohexyl-carbodiimide; acetone; In dichloromethane;
DOI:10.1021/jm00026a004