2-diazo-3-methylcyclohexanone

Base Information

Chemical Name:2-diazo-3-methylcyclohexanone
CAS No.:1381783-51-2
Molecular Formula:C₇H₁₀N₂O
Molecular Weight:138.169
Hs Code.:

Synonyms:2-diazo-3-methylcyclohexanone

Suppliers and Price of 2-diazo-3-methylcyclohexanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-diazo-3-methylcyclohexanone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-diazo-3-methylcyclohexanone

There total 2 articles about 2-diazo-3-methylcyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2-azido-3-methylcyclohexanone

: 1381783-51-2
2-diazo-3-methylcyclohexanone

Guidance literature:: With 3-(diphenylphosphaneyl)propanoic acid N-hydroxysuccinimide ether; In tetrahydrofuran; water; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1021/ja3046712

Reference yield:

: 74173-18-5,83149-31-9,55373-58-5
trimethyl(3-methylcyclohex-1-enyloxy)silane

: 1381783-51-2
2-diazo-3-methylcyclohexanone

Guidance literature:: Multi-step reaction with 3 steps

1: N-Bromosuccinimide; sodium hydrogencarbonate / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

2: sodium azide / N,N-dimethyl-formamide / 14 h / 20 °C / Inert atmosphere

3: 3-(diphenylphosphaneyl)propanoic acid N-hydroxysuccinimide ether / tetrahydrofuran; water / 3 h / 20 °C / Inert atmosphere

With N-Bromosuccinimide; sodium azide; sodium hydrogencarbonate; 3-(diphenylphosphaneyl)propanoic acid N-hydroxysuccinimide ether; In tetrahydrofuran; water; N,N-dimethyl-formamide;
DOI:10.1021/ja3046712

Reference yield: 61.0%

: 1073-67-2,24991-47-7
4-vinylbenzyl chloride

: 1381783-51-2
2-diazo-3-methylcyclohexanone

: 2-(2-(4-chlorophenyl)cyclopropyl)-3α-methylcyclohexanone

: 2β-(2β-(4-chlorophenyl)cyclopropyl)-3α-methylcyclohexanone

Guidance literature:: With rhodium(II) pivalate; In dichloromethane; at -50 ℃; for 1h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/ja3046712