cis-endo-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid monohydrate

Base Information

Chemical Name:cis-endo-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid monohydrate
CAS No.:104308-53-4
Molecular Formula:C₈H₁₃NO₂
Molecular Weight:155.197
Hs Code.:
European Community (EC) Number:635-173-7
Mol file:104308-53-4.mol

Synonyms:J-001144;cis-endo-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid monohydrate

Suppliers and Price of cis-endo-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid monohydrate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
cis-endo-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid hydrate ≥97.0% (CHN)
500mg
$ 528.00

American Custom Chemicals Corporation
3-ENDO-AMINOBICYCLO[2.2.1]HEPTANE-2-ENDO-CARBOXYLIC ACID HYDRATE 95.00%
5G
$ 3892.93

American Custom Chemicals Corporation
3-ENDO-AMINOBICYCLO[2.2.1]HEPTANE-2-ENDO-CARBOXYLIC ACID HYDRATE 95.00%
1G
$ 1467.43

American Custom Chemicals Corporation
3-ENDO-AMINOBICYCLO[2.2.1]HEPTANE-2-ENDO-CARBOXYLIC ACID HYDRATE 95.00%
100MG
$ 697.34

Total 9 raw suppliers

Chemical Property of cis-endo-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid monohydrate

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Melting Point:~275 °C (dec.)
Refractive Index:1.4890 (estimate)
Boiling Point:303.376°C at 760 mmHg
Flash Point:137.277°C
PSA：63.32000
Density:1.241g/cm³
LogP:1.14470
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:173.10519334
Heavy Atom Count:12
Complexity:193

Purity/Quality:

98%,99%, ^*data from raw suppliers

cis-endo-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid hydrate ≥97.0% (CHN) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2CC1C(C2N)C(=O)O.O
Isomeric SMILES:C1CC2CC1[C@@H]([C@@H]2N)C(=O)O.O

Technology Process of cis-endo-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid monohydrate

There total 3 articles about cis-endo-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid monohydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14805-28-8,101090-85-1
2-benzenesulfonyloxy-(3ac,7ac)-hexahydro-4r,7c-methano-isoindole-1,3-dione

: 76198-36-2,88330-32-9,104308-53-4,125109-73-1,202280-02-2,202280-03-3
di-endo-3-aminobicyclo[2.2.1]heptane-2-carboxylic acid

Guidance literature:: With sodium hydroxide;
DOI:10.1021/jo01091a035

Reference yield:

: 68330-42-7
N-hydroxy-5-norbornene-endo-2,3-dicarboxamide

: 76198-36-2,88330-32-9,104308-53-4,125109-73-1,202280-02-2,202280-03-3
di-endo-3-aminobicyclo[2.2.1]heptane-2-carboxylic acid

Guidance literature:: Multi-step reaction with 2 steps

1: chloroform; triethylamine

2: aqueous NaOH

With sodium hydroxide; chloroform; triethylamine;
DOI:10.1021/jo01091a035

Reference yield:

: 17812-27-0,853658-14-7
cis-5-norbornene-endo-2,3-dicarboxylic anhydride

: 76198-36-2,88330-32-9,104308-53-4,125109-73-1,202280-02-2,202280-03-3
di-endo-3-aminobicyclo[2.2.1]heptane-2-carboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: water; hydroxylamine

2: chloroform; triethylamine

3: aqueous NaOH

With sodium hydroxide; chloroform; water; hydroxylamine; triethylamine;
DOI:10.1021/jo01091a035