mercury bis(phenyltellurolate)

Base Information

• Chemical Name: mercury bis(phenyltellurolate)
• CAS No.: 97671-41-5
• Molecular Formula: C₁₂H₁₀HgTe₂
• Molecular Weight: 610.001
• Mol file: 97671-41-5.mol

Synonyms:mercury bis(phenyltellurolate)

Chemical Property of mercury bis(phenyltellurolate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mercury bis(phenyltellurolate)

There total 2 articles about mercury bis(phenyltellurolate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

benzenetellurolate lithium salt (52251-60-2) + mercury dichloride → mercury bis(phenyltellurolate) (97671-41-5)

Guidance literature:

In tetrahydrofuran; HgCl2 soln. was added to PhTeLi soln. at room temp. and stirred for 30 min; filtration and washing gave crude product, purifn. by extn. with toluene/PMe3 10:1 vol. and drying;

DOI:10.1021/ja00257a055

Reference yield:

→ mercury bis(phenyltellurolate) (97671-41-5)

Guidance literature:

Diphenyl-ditellurid, Quecksilber;

DOI:10.1016/S0022-328X(00)87494-X

Reference yield: 100.0%

Hg(P(C4H9)3)2(2+)*2ClO4(1-) = Hg(P(C4H9)3)2(ClO4)2 + tributylphosphine (998-40-3) + mercury bis(phenyltellurolate) (97671-41-5) → {(μ-TePh)6Hg4(P(C4H9)3)4}(ClO4)2

Guidance literature:

In dichloromethane; molar ratio of Hg(PBu3)2(ClO4)2/Hg(TePh)2/PBu3 = 1:3:2; not isolated;

upstream raw materials:

benzenetellurolate lithium salt

Downstream raw materials:

mercury(II) telluride

diphenyl telluride