4-Bromo-benzoic acid (1S,3S,4R)-3,4-dimethyl-2-methylene-3-(3-methyl-pentyl)-cyclohexyl ester

Base Information

Chemical Name:4-Bromo-benzoic acid (1S,3S,4R)-3,4-dimethyl-2-methylene-3-(3-methyl-pentyl)-cyclohexyl ester
CAS No.:86160-88-5
Molecular Formula:C₂₂H₃₁BrO₂
Molecular Weight:407.391
Hs Code.:

Synonyms:4-Bromo-benzoic acid (1S,3S,4R)-3,4-dimethyl-2-methylene-3-(3-methyl-pentyl)-cyclohexyl ester

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Chemical Property of 4-Bromo-benzoic acid (1S,3S,4R)-3,4-dimethyl-2-methylene-3-(3-methyl-pentyl)-cyclohexyl ester

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Technology Process of 4-Bromo-benzoic acid (1S,3S,4R)-3,4-dimethyl-2-methylene-3-(3-methyl-pentyl)-cyclohexyl ester

There total 7 articles about 4-Bromo-benzoic acid (1S,3S,4R)-3,4-dimethyl-2-methylene-3-(3-methyl-pentyl)-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 83920-96-1
(+)-striatene

: 86160-88-5
4-Bromo-benzoic acid (1S,3S,4R)-3,4-dimethyl-2-methylene-3-(3-methyl-pentyl)-cyclohexyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 55 mg / m-chloroperbenzoic acid / CH₂Cl₂ / 0.67 h / 0 °C

2: 7 mg / H₂ / 10percent Pd/C / ethanol / 5 h / 760 Torr / Ambient temperature

3: 14 mg / butyllithium, Et₂NH / diethyl ether; hexane / 3 h / Heating

4: 8 mg / pyridine / 24 h / Ambient temperature

With pyridine; n-butyllithium; hydrogen; diethylamine; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; In diethyl ether; ethanol; hexane; dichloromethane;
DOI:10.1246/bcsj.56.1125

Reference yield:

: (1R,2S,3R)-1,2,3-Trimethyl-2-((Z)-3-methyl-penta-2,4-dienyl)-7-oxa-bicyclo[4.1.0]heptane

: 86160-88-5
4-Bromo-benzoic acid (1S,3S,4R)-3,4-dimethyl-2-methylene-3-(3-methyl-pentyl)-cyclohexyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 7 mg / H₂ / 10percent Pd/C / ethanol / 5 h / 760 Torr / Ambient temperature

2: 14 mg / butyllithium, Et₂NH / diethyl ether; hexane / 3 h / Heating

3: 8 mg / pyridine / 24 h / Ambient temperature

With pyridine; n-butyllithium; hydrogen; diethylamine; palladium on activated charcoal; In diethyl ether; ethanol; hexane;
DOI:10.1246/bcsj.56.1125

Reference yield:

: 83920-97-2
striatol

: 86160-88-5
4-Bromo-benzoic acid (1S,3S,4R)-3,4-dimethyl-2-methylene-3-(3-methyl-pentyl)-cyclohexyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: POCl₃ / pyridine

2: MCPBA / CH₂Cl₂ / 0 °C

3: hydrogene / Pd/C

4: diethylamine, n-BuLi / diethyl ether

5: pyridine

With n-butyllithium; hydrogen; diethylamine; 3-chloro-benzenecarboperoxoic acid; trichlorophosphate; palladium on activated charcoal; In pyridine; diethyl ether; dichloromethane;
DOI:10.1246/cl.1982.1625