(1R,2S,SR)-1-methyl-2-(methylsulfinyl)-2-phenyl-1-(triphenylsilyloxy)ethane

Base Information

Chemical Name:(1R,2S,SR)-1-methyl-2-(methylsulfinyl)-2-phenyl-1-(triphenylsilyloxy)ethane
CAS No.:135559-48-7
Molecular Formula:C₂₈H₂₈O₂SSi
Molecular Weight:456.681
Hs Code.:

Synonyms:(1R,2S,SR)-1-methyl-2-(methylsulfinyl)-2-phenyl-1-(triphenylsilyloxy)ethane

Suppliers and Price of (1R,2S,SR)-1-methyl-2-(methylsulfinyl)-2-phenyl-1-(triphenylsilyloxy)ethane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2S,SR)-1-methyl-2-(methylsulfinyl)-2-phenyl-1-(triphenylsilyloxy)ethane

Chemical Property:

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Technology Process of (1R,2S,SR)-1-methyl-2-(methylsulfinyl)-2-phenyl-1-(triphenylsilyloxy)ethane

There total 2 articles about (1R,2S,SR)-1-methyl-2-(methylsulfinyl)-2-phenyl-1-(triphenylsilyloxy)ethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 126956-64-7
(1-Methyl-2-methylsulfanyl-2-phenyl-ethoxy)-triphenyl-silane

: 126956-73-8,127061-33-0,135559-48-7,135559-49-8
(2-Methanesulfinyl-1-methyl-2-phenyl-ethoxy)-triphenyl-silane

Guidance literature:: With titanium(IV) isopropylate; Cumene hydroperoxide; (+)-Weinsaeure-diethylester; In 1,2-dichloro-ethane; at -20 ℃; for 16h;
DOI:10.1016/S0040-4039(01)80528-1

Reference yield:

: 126956-64-7
(1RS,2SR)-1-methyl-2-(methylthio)-2-phenyl-1-(triphenylsilyloxy)ethane

: 135559-48-7
(1R,2S,SR)-1-methyl-2-(methylsulfinyl)-2-phenyl-1-(triphenylsilyloxy)ethane

Guidance literature:: With titanium(IV) isopropylate; diethyl (2R,3R)-tartrate; Cumene hydroperoxide; In 1,2-dichloro-ethane; at -20 ℃; for 16h; Product distribution; other protected and unprotected S-methyl-β-hydroxythioethers, other alkylhydroperoxide; the diastereoselectivity and the enantioselectivity of oxidation;
DOI:10.1016/S0957-4166(00)80048-8