Technology Process of C41H58O6Si2
There total 9 articles about C41H58O6Si2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
triphenylphosphine; diethylazodicarboxylate;
In
toluene;
at 0 - 20 ℃;
Inert atmosphere;
DOI:10.1021/ml1001807
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere
1.2: -78 - 20 °C / Inert atmosphere
2.1: n-butyllithium / tetrahydrofuran / -78 - -10 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere
3.1: 1H-imidazole / N,N-dimethyl-formamide / 15 h / 20 °C / Inert atmosphere
4.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 5 h / 20 °C / Inert atmosphere
4.2: Inert atmosphere
4.3: 19 h / Inert atmosphere; Reflux
5.1: hydrogen / ethyl acetate / 0.83 h / 5625.56 Torr / Inert atmosphere
6.1: methanol; water; sodium hydroxide / 21 h / 87 °C / Inert atmosphere
7.1: triphenylphosphine; diethylazodicarboxylate / toluene / 0 - 20 °C / Inert atmosphere
With
1H-imidazole; methanol; n-butyllithium; oxalyl dichloride; water; hydrogen; dimethyl sulfoxide; 9-bora-bicyclo[3.3.1]nonane; triphenylphosphine; sodium hydroxide; diethylazodicarboxylate;
In
tetrahydrofuran; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene;
1.1: Swern oxidation / 1.2: Swern oxidation / 4.1: Suzuki Miyaura coupling / 4.2: Suzuki Miyaura coupling / 4.3: Suzuki Miyaura coupling / 7.1: Mitsunobu reaction;
DOI:10.1021/ml1001807
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: water; toluene-4-sulfonic acid / tetrahydrofuran / 10 h / 20 °C / Inert atmosphere
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran / -78 - -10 °C / Inert atmosphere
3.2: -78 - 20 °C / Inert atmosphere
4.1: 1H-imidazole / N,N-dimethyl-formamide / 15 h / 20 °C / Inert atmosphere
5.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 5 h / 20 °C / Inert atmosphere
5.2: Inert atmosphere
5.3: 19 h / Inert atmosphere; Reflux
6.1: hydrogen / ethyl acetate / 0.83 h / 5625.56 Torr / Inert atmosphere
7.1: methanol; water; sodium hydroxide / 21 h / 87 °C / Inert atmosphere
8.1: triphenylphosphine; diethylazodicarboxylate / toluene / 0 - 20 °C / Inert atmosphere
With
1H-imidazole; methanol; n-butyllithium; oxalyl dichloride; water; hydrogen; toluene-4-sulfonic acid; dimethyl sulfoxide; 9-bora-bicyclo[3.3.1]nonane; triphenylphosphine; sodium hydroxide; diethylazodicarboxylate;
In
tetrahydrofuran; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene;
2.1: Swern oxidation / 2.2: Swern oxidation / 5.1: Suzuki Miyaura coupling / 5.2: Suzuki Miyaura coupling / 5.3: Suzuki Miyaura coupling / 8.1: Mitsunobu reaction;
DOI:10.1021/ml1001807
