1-acetoxy-5.9-dibensenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,6-nonadiene

Base Information

Chemical Name:1-acetoxy-5.9-dibensenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,6-nonadiene
CAS No.:475558-35-1
Molecular Formula:C₃₄H₄₄O₆S₂
Molecular Weight:612.852
Hs Code.:

Synonyms:1-acetoxy-5.9-dibensenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,6-nonadiene

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Chemical Property of 1-acetoxy-5.9-dibensenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,6-nonadiene

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Technology Process of 1-acetoxy-5.9-dibensenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,6-nonadiene

There total 4 articles about 1-acetoxy-5.9-dibensenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,6-nonadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 24529-80-4
(E)-1-O-acetyl-4-chloro-3-methyl-2-buten-1-ol

: 433702-96-6
3-methyl-5-(2,6,6ptrimethyl-1-cyclohexenyl)-1,5-dibenzenesulfonyl-2-pentene

: 475558-35-1
1-acetoxy-5.9-dibensenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,6-nonadiene

Guidance literature:: 3-methyl-5-(2,6,6ptrimethyl-1-cyclohexenyl)-1,5-dibenzenesulfonyl-2-pentene; With potassium tert-butylate; In N,N-dimethyl-formamide; at -20 ℃; for 1h;

(E)-1-O-acetyl-4-chloro-3-methyl-2-buten-1-ol; In N,N-dimethyl-formamide; at -20 ℃; for 3h; Further stages.;
DOI:10.1016/j.tet.2004.09.002

Reference yield:

: 56691-74-8
{[(2,6,6-trimethyl-1-cyclohexen-1-yl)methyl]sulfonyl}benzene

: 475558-35-1
1-acetoxy-5.9-dibensenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,6-nonadiene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 1 h / 0 °C

1.2: 87 percent / tetrahydrofuran; hexane / 1.5 h / 0 °C

2.1: 72 percent / LiNbMoO₆; aq. H₂O₂ / methanol; benzene / 6 h / 25 °C

3.1: t-BuOK / dimethylformamide / 1 h / -20 °C

3.2: 85 percent / dimethylformamide / 3 h / -20 °C

With n-butyllithium; LiNbMoO₆; potassium tert-butylate; dihydrogen peroxide; In tetrahydrofuran; methanol; hexane; N,N-dimethyl-formamide; benzene; 3.2: Julia olefination;
DOI:10.1016/j.tet.2004.09.002

Reference yield:

: 433702-92-2
C₂₇H₃₄O₂S₂

: 475558-35-1
1-acetoxy-5.9-dibensenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,6-nonadiene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 72 percent / LiNbMoO₆; aq. H₂O₂ / methanol; benzene / 6 h / 25 °C

2.1: t-BuOK / dimethylformamide / 1 h / -20 °C

2.2: 85 percent / dimethylformamide / 3 h / -20 °C

With LiNbMoO₆; potassium tert-butylate; dihydrogen peroxide; In methanol; N,N-dimethyl-formamide; benzene; 2.2: Julia olefination;
DOI:10.1016/j.tet.2004.09.002