((2R,3S,6S)-6-Allyloxy-3-prop-2-ynyloxy-3,6-dihydro-2H-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane

Base Information

Chemical Name:((2R,3S,6S)-6-Allyloxy-3-prop-2-ynyloxy-3,6-dihydro-2H-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane
CAS No.:187164-24-5
Molecular Formula:C₂₈H₃₄O₄Si
Molecular Weight:462.661
Hs Code.:

Synonyms:((2R,3S,6S)-6-Allyloxy-3-prop-2-ynyloxy-3,6-dihydro-2H-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane

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Chemical Property of ((2R,3S,6S)-6-Allyloxy-3-prop-2-ynyloxy-3,6-dihydro-2H-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane

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Technology Process of ((2R,3S,6S)-6-Allyloxy-3-prop-2-ynyloxy-3,6-dihydro-2H-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane

There total 3 articles about ((2R,3S,6S)-6-Allyloxy-3-prop-2-ynyloxy-3,6-dihydro-2H-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 106-96-7
propargyl bromide

: 183273-88-3
(2R,3S,6S)-6-Allyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-ol

: 187164-24-5
((2R,3S,6S)-6-Allyloxy-3-prop-2-ynyloxy-3,6-dihydro-2H-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane

Guidance literature:: With sodium hydride; In tetrahydrofuran; Ambient temperature;
DOI:10.1021/jo961138w

Reference yield:

: 121703-30-8,149342-23-4,67079-54-3
prop-2-enyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythrohex-2-enopyranoside

: 187164-24-5
((2R,3S,6S)-6-Allyloxy-3-prop-2-ynyloxy-3,6-dihydro-2H-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / CH₃ONa / methanol / 2 h / Ambient temperature

2: 66 percent / imidazole / dimethylformamide / Ambient temperature

3: 96 percent / NaH / tetrahydrofuran / Ambient temperature

With 1H-imidazole; sodium methylate; sodium hydride; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1021/jo961138w

Reference yield:

: 67079-55-4
prop-2-en-1-yl 2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

: 187164-24-5
((2R,3S,6S)-6-Allyloxy-3-prop-2-ynyloxy-3,6-dihydro-2H-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 66 percent / imidazole / dimethylformamide / Ambient temperature

2: 96 percent / NaH / tetrahydrofuran / Ambient temperature

With 1H-imidazole; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jo961138w