1,1-di-tert-butyl-2-(3-methoxy-2-triisopropylsilanyloxy-benzyl)-silirane

Base Information

• Chemical Name: 1,1-di-tert-butyl-2-(3-methoxy-2-triisopropylsilanyloxy-benzyl)-silirane
• CAS No.: 457912-91-3
• Molecular Formula: C₂₇H₅₀O₂Si₂
• Molecular Weight: 462.864

Synonyms:1,1-di-tert-butyl-2-(3-methoxy-2-triisopropylsilanyloxy-benzyl)-silirane

Chemical Property of 1,1-di-tert-butyl-2-(3-methoxy-2-triisopropylsilanyloxy-benzyl)-silirane

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 1,1-di-tert-butyl-2-(3-methoxy-2-triisopropylsilanyloxy-benzyl)-silirane

There total 4 articles about 1,1-di-tert-butyl-2-(3-methoxy-2-triisopropylsilanyloxy-benzyl)-silirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

7,7-di-tert-butyl-7-silabicyclo[4.1.0]heptane (130451-35-3) + (2-allyl-6-methoxy-phenoxy)-triisopropyl-silane (457912-86-6) → 1,1-di-tert-butyl-2-(3-methoxy-2-triisopropylsilanyloxy-benzyl)-silirane (457912-91-3)

Guidance literature:

With silver trifluoromethanesulfonate; In ⁽²⁾H₈-toluene; at -27 ℃; for 2h;

DOI:10.1021/ja020566i

Reference yield:

triisopropylsilyl chloride (13154-24-0) → 1,1-di-tert-butyl-2-(3-methoxy-2-triisopropylsilanyloxy-benzyl)-silirane (457912-91-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 88 percent / imidazole / dimethylformamide / 56 h

2: 72 percent Spectr_. / AgOTf / toluene-d8 / 2 h / -27 °C

With 1H-imidazole; silver trifluoromethanesulfonate; In ⁽²⁾H₈-toluene; N,N-dimethyl-formamide;

DOI:10.1021/ja020566i

Reference yield:

6-allylguaicol (579-60-2) → 1,1-di-tert-butyl-2-(3-methoxy-2-triisopropylsilanyloxy-benzyl)-silirane (457912-91-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 88 percent / imidazole / dimethylformamide / 56 h

2: 72 percent Spectr_. / AgOTf / toluene-d8 / 2 h / -27 °C

With 1H-imidazole; silver trifluoromethanesulfonate; In ⁽²⁾H₈-toluene; N,N-dimethyl-formamide;

DOI:10.1021/ja020566i

upstream raw materials:

7,7-di-tert-butyl-7-silabicyclo[4.1.0]heptane

(2-allyl-6-methoxy-phenoxy)-triisopropyl-silane

(1R,6S)-7,7-Di-tert-butyl-7-sila-bicyclo[4.1.0]heptane

triisopropylsilyl chloride

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