9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal

Base Information

• Chemical Name: 9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal
• CAS No.: 80627-94-7
• Molecular Formula: C₂₀H₂₅NO₅
• Molecular Weight: 359.422

Synonyms:9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal

Chemical Property of 9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal

There total 5 articles about 9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

9-(carbophenoxy)-2,6-dioxo-9-azabicyclo<3.3.1>nonane-2,6-dione (80627-99-2) + 9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione bis(2,2-dimethylpropylene) ketal (80627-95-8) → 9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal (80627-94-7)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; for 5h; Heating;

DOI:10.1021/jo00345a004

Reference yield:

N-methyl-2,6-diacetoxy-9-azabicyclo<3.3.1>nonane (57639-00-6) → 9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal (80627-94-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 71 percent / LiI / acetone / 1.) 0 deg C, 2.) 25 deg C, 3.5 h

2: 98 percent / K₂CO₃ / methanol; H₂O / 2 h / Ambient temperature

3: 56.4 percent / pyridinium chlorochromate (PCC) / CHCl₃ / 26 h / 25 °C

4: 58 percent / toluenesulfonic acid monohydrate / toluene / 5 h / Heating

With potassium carbonate; toluene-4-sulfonic acid; pyridinium chlorochromate; lithium iodide; In methanol; chloroform; water; acetone; toluene;

DOI:10.1021/jo00345a004

Reference yield:

9-(carbophenoxy)-endo,endo-2,6-dihydroxy-9-azabicyclo<3.3.1>nonane (80628-00-8) → 9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal (80627-94-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 56.4 percent / pyridinium chlorochromate (PCC) / CHCl₃ / 26 h / 25 °C

2: 58 percent / toluenesulfonic acid monohydrate / toluene / 5 h / Heating

With toluene-4-sulfonic acid; pyridinium chlorochromate; In chloroform; toluene;

DOI:10.1021/jo00345a004

upstream raw materials:

9-(carbophenoxy)-2,6-dioxo-9-azabicyclo<3.3.1>nonane-2,6-dione

9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione bis(2,2-dimethylpropylene) ketal

N-methyl-2,6-diacetoxy-9-azabicyclo<3.3.1>nonane

9-(carbophenoxy)-endo,endo-2,6-dihydroxy-9-azabicyclo<3.3.1>nonane

Downstream raw materials:

5-methyl-12-(carbophenoxy)-6,7,8,9,10,11-hexahydro-6,10-imino-5H-cyclooctindol-9-one

C₂₆H₂₈N₂O₅

C₂₆H₂₈N₂O₄S₂

spiro<5-methyl-12-(carbophenoxy)-6,7,8,9,10,11-hexahydro-6,10-imino-5H-cyclooctindole-9,2':1',3'-dioxep-5'-ene>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 80627-94-7 9-(carbophenoxy)-9-azabicyclo<3.3.1>nonane-2,6-dione 2,2-dimethylpropylene ketal

Send

Send

Metric Ton KG G Pound L ML

Send

Send