syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

Base Information

Chemical Name:syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate
CAS No.:83153-10-0
Molecular Formula:C₁₅H₁₈O₄S
Molecular Weight:294.372
Hs Code.:

syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0<sup>2,4</sup>>oct-anti-8-yl p-toluenesulfonate

Synonyms:syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

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Chemical Property of syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

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Technology Process of syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

There total 3 articles about syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 98-59-9
p-toluenesulfonyl chloride

: 83153-12-2
syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>octan-anti-8-ol

: 83153-10-0
syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

Guidance literature:: With n-butyllithium; 1.) THF, dry ice-isopropanol bath, 5 min, 2.) 15 min; -> 0 deg C; 0 deg C, 45 min;
DOI:10.1021/ja00387a043

Reference yield:

: 694-71-3
bicyclo<2.2.1>hept-2-en-7-one

: 83153-10-0
syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

Guidance literature:: Multi-step reaction with 3 steps

2: m-chloroperbenzoic acid / CH₂Cl₂ / 18 h

3: 42 percent / 1.) n-BuLi / 1.) THF, dry ice-isopropanol bath, 5 min, 2.) 15 min; -> 0 deg C; 0 deg C, 45 min

With n-butyllithium; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/ja00387a043

Reference yield:

: syn-7-methylbicyclo<2.2.1>hept-2-en-anti-7-ol

: 83153-10-0
syn-8-methyl-3-oxa-endo-tricyclo<3.2.1.0^2,4>oct-anti-8-yl p-toluenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: m-chloroperbenzoic acid / CH₂Cl₂ / 18 h

2: 42 percent / 1.) n-BuLi / 1.) THF, dry ice-isopropanol bath, 5 min, 2.) 15 min; -> 0 deg C; 0 deg C, 45 min

With n-butyllithium; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/ja00387a043