5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylsulfonyl)-1-phenyl-1H-tetrazole

Base Information

Chemical Name:5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylsulfonyl)-1-phenyl-1H-tetrazole
CAS No.:1234572-98-5
Molecular Formula:C₂₅H₄₂N₄O₅SSi
Molecular Weight:538.784
Hs Code.:

Synonyms:5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylsulfonyl)-1-phenyl-1H-tetrazole

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Chemical Property of 5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylsulfonyl)-1-phenyl-1H-tetrazole

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Technology Process of 5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylsulfonyl)-1-phenyl-1H-tetrazole

There total 10 articles about 5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylsulfonyl)-1-phenyl-1H-tetrazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1234573-19-3
5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylthio)-1-phenyl-1H-tetrazole

: 1234572-98-5
5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylsulfonyl)-1-phenyl-1H-tetrazole

Guidance literature:: With ammonium heptamolybdate tetrahydrate; dihydrogen peroxide; In ethanol; at 0 - 20 ℃;
DOI:10.1002/chem.201000428

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 1234572-98-5
5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylsulfonyl)-1-phenyl-1H-tetrazole

Guidance literature:: Multi-step reaction with 4 steps

1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 - 20 °C

2: acetic acid / tetrahydrofuran; water / 6 h / 20 °C

3: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 1 h / -20 °C

4: ammonium molybdate; dihydrogen peroxide / ethanol / 12 h / 0 - 20 °C

With 2,6-dimethylpyridine; ammonium molybdate; di-isopropyl azodicarboxylate; dihydrogen peroxide; acetic acid; triphenylphosphine; In tetrahydrofuran; ethanol; dichloromethane; water; 3: Mitsunobu reaction;
DOI:10.1002/asia.201100429

Reference yield:

: 1234573-15-9
(S)-10,10,11,11-tetramethyl-5-((S)-oxiran-2-yl)-2,4,9-trioxa-10-siladodecane

: 1234572-98-5
5-((4S,5S)-4-(methoxymethoxy)-5-(triisopropylsilyloxy)hept-6-enylsulfonyl)-1-phenyl-1H-tetrazole

Guidance literature:: Multi-step reaction with 5 steps

1: n-butyllithium / tetrahydrofuran / 1 h / -18 - 20 °C

2: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 - 20 °C

3: acetic acid / tetrahydrofuran; water / 6 h / 20 °C

4: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 1 h / -20 °C

5: ammonium molybdate; dihydrogen peroxide / ethanol / 12 h / 0 - 20 °C

With 2,6-dimethylpyridine; n-butyllithium; ammonium molybdate; di-isopropyl azodicarboxylate; dihydrogen peroxide; acetic acid; triphenylphosphine; In tetrahydrofuran; ethanol; dichloromethane; water; 4: Mitsunobu reaction;
DOI:10.1002/asia.201100429