2-methoxy-5-benzyloxyphenyl-tetra-O-acetyl-β-D-glucopyranoside

Base Information

• Chemical Name: 2-methoxy-5-benzyloxyphenyl-tetra-O-acetyl-β-D-glucopyranoside
• CAS No.: 251921-29-6
• Molecular Formula: C₂₈H₃₂O₁₂
• Molecular Weight: 560.555
• Mol file: 251921-29-6.mol

Synonyms:2-methoxy-5-benzyloxyphenyl-tetra-O-acetyl-β-D-glucopyranoside

Chemical Property of 2-methoxy-5-benzyloxyphenyl-tetra-O-acetyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2-methoxy-5-benzyloxyphenyl-tetra-O-acetyl-β-D-glucopyranoside

There total 1 articles about 2-methoxy-5-benzyloxyphenyl-tetra-O-acetyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

2-methoxy-5-benzyloxyphenol (84354-17-6) + 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (572-09-8) → 2-methoxy-5-benzyloxyphenyl-tetra-O-acetyl-β-D-glucopyranoside (251921-29-6)

Guidance literature:

With sodium hydroxide; benzyltriethylammonium bromide; In chloroform; at 60 ℃; for 13h;

DOI:10.1021/np9902237

Reference yield: 42.0%

2-methoxy-5-benzyloxyphenyl-tetra-O-acetyl-β-D-glucopyranoside (251921-29-6) → 2-hydroxy-5-benzyloxyphenyl-O-β-D-glucopyranoside (1053700-12-1)

Guidance literature:

With sodium thioethoxide; In N,N-dimethyl-formamide;

DOI:10.1021/np9902237

Reference yield:

2-methoxy-5-benzyloxyphenyl-tetra-O-acetyl-β-D-glucopyranoside (251921-29-6) → 2,5-dihydroxyphenyl-O-β-D-glucopyranoside

Guidance literature:

Multi-step reaction with 2 steps

1: 42 percent / sodium thioethoxide / dimethylformamide

2: cyclohexene; palladium hydroxide / ethanol / 3 h / Heating

With palladium dihydroxide; sodium thioethoxide; cyclohexene; In ethanol; N,N-dimethyl-formamide; 1: Hydrolysis / 2: Elimination;

DOI:10.1021/np9902237

upstream raw materials:

2-methoxy-5-benzyloxyphenol

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

Downstream raw materials:

2-hydroxy-5-benzyloxyphenyl-O-β-D-glucopyranoside