(S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal

Base Information

Chemical Name:(S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal
CAS No.:903516-22-3
Molecular Formula:C₂₇H₄₃NO₅SSi
Molecular Weight:521.794
Hs Code.:

Synonyms:(S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal

Suppliers and Price of (S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal

There total 4 articles about (S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 96994-77-3
3-iodopropionaldehyde dimethylacetal

: 143260-53-1
(S)-N-[1-benzyl-2-(tert-butyldimethylsilyloxy)ethyl]-p-toluenesulfonamide

: 903516-22-3
(S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; at 25 ℃; for 72h;
DOI:10.1021/jo060495w

Reference yield:

: 3182-95-4
L-Phenylalaninol

: 903516-22-3
(S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / DMAP; triethylamine / CH₂Cl₂ / 0 - 25 °C

2: 99 percent / imidazole / dimethylformamide / 0 - 25 °C

3: 89 percent / Cs₂CO₃ / dimethylformamide / 72 h / 25 °C

With 1H-imidazole; dmap; caesium carbonate; triethylamine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo060495w

Reference yield:

: 82495-70-3
(2S)-2-p-toluenesulfonamido-3-phenylpropanol

: 903516-22-3
(S)-4-aza-6-(tert-butyldimethylsilanyloxy)-5-benzyl-4-(p-toluenesulfonyl)hexanal dimethyl acetal

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / imidazole / dimethylformamide / 0 - 25 °C

2: 89 percent / Cs₂CO₃ / dimethylformamide / 72 h / 25 °C

With 1H-imidazole; caesium carbonate; In N,N-dimethyl-formamide;
DOI:10.1021/jo060495w