(1R,2R,3S,4S)-<3--2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate

Base Information

Chemical Name:(1R,2R,3S,4S)-<3--2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate
CAS No.:170117-08-5
Molecular Formula:C₃₇H₄₃NO₅S
Molecular Weight:613.818
Hs Code.:

(1R,2R,3S,4S)-<3-<N-benzenesulfonyl-N-(3,5-dimethylphenyl)-amino>-2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate

Synonyms:(1R,2R,3S,4S)-<3--2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2R,3S,4S)-<3--2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate

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Technology Process of (1R,2R,3S,4S)-<3--2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate

There total 5 articles about (1R,2R,3S,4S)-<3--2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 591-51-5
phenyllithium

: 170117-11-0
(1R,2R,3S,4S)-<3--2-bornyl>-2-oxo-cyclohexenecarboxylate

: 170117-08-5
(1R,2R,3S,4S)-<3--2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate

Guidance literature:: With thien-2-yl(cyano)copper lithium; In tetrahydrofuran; diethyl ether; hexane; at -78 ℃; for 2h;
DOI:10.1016/0040-4020(95)00676-Y

Reference yield:

: 87360-02-9
N-(3,5-Dimethyl-phenyl)-N-((1S,2S,3R,4R)-3-hydroxy-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-benzenesulfonamide

: 170117-08-5
(1R,2R,3S,4S)-<3--2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: 94 percent / DMAP / toluene / 48 h / Heating

2: pyridine / CH₂Cl₂ / 2 h / 20 °C

3: 91 percent / mCPBA / CH₂Cl₂ / 2 h / 20 °C

4: 66 percent / lithium 2-thienyl-cyanocuprate / tetrahydrofuran; hexane; diethyl ether / 2 h / -78 °C

With pyridine; dmap; thien-2-yl(cyano)copper lithium; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; toluene;
DOI:10.1016/0040-4020(95)00676-Y

Reference yield:

: 170116-93-5
(1R,2R,3S,4S)-<3--2-bornyl>-2-hydroxy-cyclohexenecarboxylate

: 170117-08-5
(1R,2R,3S,4S)-<3--2-bornyl>-(6S)-2-hydroxy-6-phenyl-cyclohexenecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / CH₂Cl₂ / 2 h / 20 °C

2: 91 percent / mCPBA / CH₂Cl₂ / 2 h / 20 °C

3: 66 percent / lithium 2-thienyl-cyanocuprate / tetrahydrofuran; hexane; diethyl ether / 2 h / -78 °C

With pyridine; thien-2-yl(cyano)copper lithium; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; diethyl ether; hexane; dichloromethane;
DOI:10.1016/0040-4020(95)00676-Y