1,4,7,13,16-pentakis(p-tolylsulfonyl)-10,22-dioxa-1,4,7,13,16,19-hexaazacyclotetracosane hydrochloride

Base Information

Chemical Name:1,4,7,13,16-pentakis(p-tolylsulfonyl)-10,22-dioxa-1,4,7,13,16,19-hexaazacyclotetracosane hydrochloride
CAS No.:134209-69-1
Molecular Formula:C₅₁H₆₈N₆O₁₂S₅*ClH
Molecular Weight:1153.92
Hs Code.:

Synonyms:1,4,7,13,16-pentakis(p-tolylsulfonyl)-10,22-dioxa-1,4,7,13,16,19-hexaazacyclotetracosane hydrochloride

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Chemical Property of 1,4,7,13,16-pentakis(p-tolylsulfonyl)-10,22-dioxa-1,4,7,13,16,19-hexaazacyclotetracosane hydrochloride

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Technology Process of 1,4,7,13,16-pentakis(p-tolylsulfonyl)-10,22-dioxa-1,4,7,13,16,19-hexaazacyclotetracosane hydrochloride

There total 5 articles about 1,4,7,13,16-pentakis(p-tolylsulfonyl)-10,22-dioxa-1,4,7,13,16,19-hexaazacyclotetracosane hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 134209-54-4
1-(diethoxyphosphoryl)-4,7,13,16,19-pentakis(p-tolylsulfonyl)-10,22,dioxa-1,4,7,13,16,19-hexaazacyclotetracosane

: 134209-69-1
1,4,7,13,16-pentakis(p-tolylsulfonyl)-10,22-dioxa-1,4,7,13,16,19-hexaazacyclotetracosane hydrochloride

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; Ambient temperature; overnight;
DOI:10.1021/jo00016a018

Reference yield:

: 4403-78-5
ditosylethylenediamine

: 134209-69-1
1,4,7,13,16-pentakis(p-tolylsulfonyl)-10,22-dioxa-1,4,7,13,16,19-hexaazacyclotetracosane hydrochloride

Guidance literature:: Multi-step reaction with 5 steps

1: NaH / DMF, 60 deg C, 1 h

2: 98 percent / borane-THF / tetrahydrofuran / 10 h / Heating

3: 100 percent / N(C₂H₅)3 / CH₂Cl₂ / 1 h / Ambient temperature

4: NaH / DMSO, 70 - 75 deg C, 2 h

5: 85 percent / HCl / tetrahydrofuran / Ambient temperature; overnight

With hydrogenchloride; borane-THF; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00016a018

Reference yield:

: 134237-97-1
N,N'-bis(p-tolylsulfonyl)diethylenetriamine

: 134209-69-1
1,4,7,13,16-pentakis(p-tolylsulfonyl)-10,22-dioxa-1,4,7,13,16,19-hexaazacyclotetracosane hydrochloride

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / N(C₂H₅)3 / CH₂Cl₂ / 1 h / Ambient temperature

2: NaH / DMSO, 70 - 75 deg C, 2 h

3: 85 percent / HCl / tetrahydrofuran / Ambient temperature; overnight

With hydrogenchloride; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00016a018