Pd(1,2-bis(dicyclohexylphosphino)ethane)(dba)

Base Information

Chemical Name:Pd(1,2-bis(dicyclohexylphosphino)ethane)(dba)
CAS No.:329791-57-3
Molecular Formula:C₄₃H₆₂OP₂Pd
Molecular Weight:763.332
Hs Code.:

Synonyms:Pd(1,2-bis(dicyclohexylphosphino)ethane)(dba)

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Chemical Property of Pd(1,2-bis(dicyclohexylphosphino)ethane)(dba)

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Technology Process of Pd(1,2-bis(dicyclohexylphosphino)ethane)(dba)

There total 2 articles about Pd(1,2-bis(dicyclohexylphosphino)ethane)(dba) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 52522-40-4
tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex

: 23743-26-2
1,2-bis-(dicyclohexylphosphino)ethane

: 329791-57-3
Pd(1,2-bis(dicyclohexylphosphino)ethane)(dba)

Guidance literature:: In benzene; byproducts: (PhCHCH)2O; (Ar); standard Schlenk technique; soln. of ligand in benzene added to soln. of Pd complex in benzene for 10 min; mixt. was kept for 1.25 h; Et2O added; filtered; crystd. (CH2Cl2-Et2O, -20°C); washed (pentane); dried in vac. at 40°C for 16 h; elem. anal.;
DOI:10.1016/S0022-328X(00)00524-6

Reference yield: 54.0%

: 32005-36-0
bis(dibenzylideneacetone)-palladium⁽⁰⁾

: 23743-26-2
1,2-bis-(dicyclohexylphosphino)ethane

: 329791-57-3
Pd(1,2-bis(dicyclohexylphosphino)ethane)(dba)

Guidance literature:: In toluene; Pd(dba)2 and dcype in toluene were stired for 3 days; solvent was removed in vacuo, residue was taken up in THF and filtered, soln. was concd., pentane was added, ppt. was washed with pentane/Et2O and dried in vacuo;
DOI:10.1021/ja010628p

Reference yield: 72.0%

: 329791-57-3
Pd(1,2-bis(dicyclohexylphosphino)ethane)(dba)

: 2-iodo-1,3,4,5-tetramethylimidazolium tetrafluoroborate

: [Pd(II)(1,3,4,5-tetramethylimidazol-2-ylidene)I(1,2-bis(dicyclohexylphosphino)ethane)]BF₄

Guidance literature:: In tetrahydrofuran; 2-iodo-1,3,4,5-tetramethylimidazoliun tetrafluoroborate and Pd(dcype)(dba) in THF were heated to 65°C for 24 h; soln. was concd., Et2O was added, ppt. was washed with THF/Et2O and et2Oand dried in vacuo; elem. anal.;
DOI:10.1021/ja010628p