C₂₆H₃₉IOSi

Base Information

• Chemical Name: C₂₆H₃₉IOSi
• CAS No.: 1454597-98-8
• Molecular Formula: C₂₆H₃₉IOSi
• Molecular Weight: 522.585
• Mol file: 1454597-98-8.mol

Synonyms:C₂₆H₃₉IOSi

Chemical Property of C₂₆H₃₉IOSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₆H₃₉IOSi

There total 9 articles about C₂₆H₃₉IOSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

C26H40O2Si → C26H39IOSi (1454597-98-8)

Guidance literature:

With 1H-imidazole; iodine; triphenylphosphine; In diethyl ether; acetonitrile; at 0 ℃; for 1h; Inert atmosphere;

DOI:10.1002/chem.201404034

Reference yield:

C22H35NO4 → C26H39IOSi (1454597-98-8)

Guidance literature:

Multi-step reaction with 4 steps

1: potassium carbonate / methanol / 24 h / 20 °C / Inert atmosphere

2: 1H-imidazole; dmap / dichloromethane / 1 h / 20 °C / Inert atmosphere

3: diisobutylaluminium hydride / hexane; tetrahydrofuran / 3 h / 0 °C / Inert atmosphere

4: triphenylphosphine; iodine; 1H-imidazole / acetonitrile; diethyl ether / 1 h / 0 °C / Inert atmosphere

With 1H-imidazole; dmap; iodine; diisobutylaluminium hydride; potassium carbonate; triphenylphosphine; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; acetonitrile;

DOI:10.1002/anie.201303776

Reference yield:

C17H26O3 (1283733-40-3) → C26H39IOSi (1454597-98-8)

Guidance literature:

Multi-step reaction with 5 steps

1: chloro-trimethyl-silane / dichloromethane / 1 h / 20 °C / Inert atmosphere

2: potassium carbonate / methanol / 24 h / 20 °C / Inert atmosphere

3: 1H-imidazole; dmap / dichloromethane / 1 h / 20 °C / Inert atmosphere

4: diisobutylaluminium hydride / hexane; tetrahydrofuran / 3 h / 0 °C / Inert atmosphere

5: triphenylphosphine; iodine; 1H-imidazole / acetonitrile; diethyl ether / 1 h / 0 °C / Inert atmosphere

With 1H-imidazole; dmap; chloro-trimethyl-silane; iodine; diisobutylaluminium hydride; potassium carbonate; triphenylphosphine; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; acetonitrile;

DOI:10.1002/anie.201303776

upstream raw materials:

C₁₇H₂₆O₃

C₁₅H₃₁NO₃

C₂₆H₃₁NO₅

C₂₇H₃₃NO₅

Downstream raw materials:

C₄₀H₆₈O₃Si

C₄₀H₆₈O₃Si

C₃₁H₅₆O₅S