hydridobis(dimethylphenylphosphine)tris(2,4,6-trimethylthiophenolato)tungsten(IV)

Base Information

Chemical Name:hydridobis(dimethylphenylphosphine)tris(2,4,6-trimethylthiophenolato)tungsten(IV)
CAS No.:125566-17-8
Molecular Formula:C₄₃H₅₆P₂S₃W
Molecular Weight:914.913
Hs Code.:

Synonyms:hydridobis(dimethylphenylphosphine)tris(2,4,6-trimethylthiophenolato)tungsten(IV)

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Chemical Property of hydridobis(dimethylphenylphosphine)tris(2,4,6-trimethylthiophenolato)tungsten(IV)

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Technology Process of hydridobis(dimethylphenylphosphine)tris(2,4,6-trimethylthiophenolato)tungsten(IV)

There total 1 articles about hydridobis(dimethylphenylphosphine)tris(2,4,6-trimethylthiophenolato)tungsten(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 1541-10-2
mesitylthiol

: 20540-07-2
tris(dimethylphenylphosphine)hexahydridotungsten

: 125566-17-8
hydridobis(dimethylphenylphosphine)tris(2,4,6-trimethylthiophenolato)tungsten(IV)

Guidance literature:: In methanol; byproducts: H2, P(CH3)2C6H5; the hydrido-complex was dissolved in MeOH, warmed at 40 °C, and 4 equiv. HSC6H2(Me)3-2,4,6 added; the mixt. was stirred under Ar for 16 h;; after filtration, the ppt was washed with MeOH and recrystd. from hot toluene; elem. anal.;;
DOI:10.1039/DT9910001813

Reference yield: 90.0%

: 125566-17-8
hydridobis(dimethylphenylphosphine)tris(2,4,6-trimethylthiophenolato)tungsten(IV)

: 125640-07-5
(dimethylphenylphosphine)hydrido(pyridine)-tris(2,4,6-trimethylthiophenolato)tungsten(IV)

Guidance literature:: With pyridine; In pyridine; stirring (60°C, overnight); cooling to room temp., evapn. (reduced pressure), dissoln. in C6H6, pptn. with MeOH;
DOI:10.1039/DT9910002519

Reference yield: 50.0%

: 125566-17-8
hydridobis(dimethylphenylphosphine)tris(2,4,6-trimethylthiophenolato)tungsten(IV)

: 75-05-8,26809-02-9
acetonitrile

: 137602-50-7
acetonitrile(dimethylphenylphosphine)hydridotris(2,4,6-triisopropylthiophenolato)tungsten(IV)

Guidance literature:: In acetonitrile; benzene; stirring (overnight); solvent removal, addn. of C6H6/CH3CN, pptn. with MeOH (after few min.);
DOI:10.1039/DT9910002519