(R)-1-phenylethyl tetradecanoate

Base Information

• Chemical Name: (R)-1-phenylethyl tetradecanoate
• CAS No.: 763132-65-6
• Molecular Formula: C₂₂H₃₆O₂
• Molecular Weight: 332.527
• Mol file: 763132-65-6.mol

Synonyms:(R)-1-phenylethyl tetradecanoate

Chemical Property of (R)-1-phenylethyl tetradecanoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R)-1-phenylethyl tetradecanoate

There total 3 articles about (R)-1-phenylethyl tetradecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vinyl myristate (5809-91-6) + 1-Phenylethanol (98-85-1,13323-81-4) → (S)-1-phenylethanol (1445-91-6) + (R)-1-phenylethanol (1517-69-7) + (R)-1-phenylethyl tetradecanoate (763132-65-6)

Guidance literature:

With CAL B; at 35 ℃; for 0.5h; optical yield given as %ee; Resolution of racemate; Enzymatic reaction;

DOI:10.1002/ejoc.201000640

Reference yield:

vinyl myristate (5809-91-6) + 1-Phenylethanol (98-85-1,13323-81-4) → (S)-1-phenylethanol (1445-91-6) + (R)-1-phenylethanol (1517-69-7) + (R)-1-phenylethyl tetradecanoate (763132-65-6) + (S)-1-phenylethyl tetradecanoate

Guidance literature:

With CAL B; at 35 ℃; for 1h; optical yield given as %ee; Ionic liquid; Resolution of racemate; Enzymatic reaction;

DOI:10.1002/ejoc.201000640

Reference yield:

1-Phenylethanol (98-85-1,13323-81-4) + 2,2,2-trifluoroethyl tetradecanoate → (S)-1-phenylethanol (1445-91-6) + (R)-1-phenylethyl tetradecanoate (763132-65-6)

Guidance literature:

With Candida antarctica lipase B; at 35 ℃; under 100 Torr; enantioselective reaction; Enzymatic reaction;

DOI:10.1016/j.tetasy.2010.05.024

upstream raw materials:

1-Phenylethanol

vinyl myristate

Refernces

• 1、 Lourenco, Nuno M. T.,Monteiro, Carlos M.,Afonso, Carlos A. M.. "Ionic acylating agents for the enzymatic resolution of sec-alcohols in ionic liquids". experimental part. p. 6938 - 6943. Retrieved 2011/02/24.