1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3-di-O-acetyl-4,6-O-benzylidene)-1-thio-β-D-galactopyranoside

Base Information

Chemical Name:1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3-di-O-acetyl-4,6-O-benzylidene)-1-thio-β-D-galactopyranoside
CAS No.:904691-60-7
Molecular Formula:C₂₄H₃₀Cl₃NO₉S
Molecular Weight:614.929
Hs Code.:

Synonyms:1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3-di-O-acetyl-4,6-O-benzylidene)-1-thio-β-D-galactopyranoside

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Chemical Property of 1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3-di-O-acetyl-4,6-O-benzylidene)-1-thio-β-D-galactopyranoside

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Technology Process of 1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3-di-O-acetyl-4,6-O-benzylidene)-1-thio-β-D-galactopyranoside

There total 3 articles about 1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3-di-O-acetyl-4,6-O-benzylidene)-1-thio-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 904691-59-4
1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(4,6-O-benzylidene)-1-thio-β-D-galactopyranoside

: 108-24-7
acetic anhydride

: 904691-60-7
1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3-di-O-acetyl-4,6-O-benzylidene)-1-thio-β-D-galactopyranoside

Guidance literature:: With pyridine; dmap; for 24h; cooling;
DOI:10.1002/anie.200600591

Reference yield:

: 904691-58-3
[2-(3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-ylsulfanyl)-ethyl]-carbamic acid 2,2,2-trichloro-1,1-dimethyl-ethyl ester

: 904691-60-7
1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3-di-O-acetyl-4,6-O-benzylidene)-1-thio-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.74 g / camphorsulfonic acid / acetonitrile / 20 °C

2: 77 percent / pyridine; DMAP / 24 h / cooling

With pyridine; dmap; camphor-10-sulfonic acid; In acetonitrile;
DOI:10.1002/anie.200600591

Reference yield:

: 1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3,4,6-tri-O-acetyl)-1-thio-β-D-galactopyranoside

: 904691-60-7
1,1-dimethyl-2,2,2-trichloroethyl N-(2-mercaptoethyl)carbamate-(2,3-di-O-acetyl-4,6-O-benzylidene)-1-thio-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: NaOMe / methanol / 8 h / 20 °C

2: 1.74 g / camphorsulfonic acid / acetonitrile / 20 °C

3: 77 percent / pyridine; DMAP / 24 h / cooling

With pyridine; dmap; camphor-10-sulfonic acid; sodium methylate; In methanol; acetonitrile;
DOI:10.1002/anie.200600591