(3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one

Base Information

Chemical Name:(3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one
CAS No.:1310802-65-3
Molecular Formula:C₂₅H₃₆O₄Si
Molecular Weight:428.644
Hs Code.:

Synonyms:(3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one

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Chemical Property of (3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one

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Technology Process of (3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one

There total 5 articles about (3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

C₂₅H₃₈O₄Si: 1310802-64-2
C₂₅H₃₈O₄Si

(3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one: 1310802-65-3
(3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 15h;
DOI:10.1016/j.tetlet.2011.03.154

Reference yield:

: 954114-83-1
(2R,3S)-3-(4-(benzyloxy)-3-methoxyphenyl)-3-((tert-butyldimethylsilyl)oxy)-2-methylpropan-1-ol

(3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one: 1310802-65-3
(3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: Dess-Martin periodane / dichloromethane / 26 h / 20 °C

2: tetrahydrofuran / 3 h / 0 °C

3: Dess-Martin periodane / dichloromethane / 15 h / 20 °C

With Dess-Martin periodane; In tetrahydrofuran; dichloromethane; 1: Dess-Martin oxidation / 2: Grignard reaction / 3: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2011.03.154

Reference yield:

: 1310802-63-1
(2S,3S)-3-(4-(benzyloxy)-3-methoxyphenyl)-3-((tert-butyldimethylsilyl)oxy)-2-methylpropanal

(3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one: 1310802-65-3
(3S,4S)-4-(4-(benzyloxy)-3-methoxyphenyl)-4-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran / 3 h / 0 °C

2: Dess-Martin periodane / dichloromethane / 15 h / 20 °C

With Dess-Martin periodane; In tetrahydrofuran; dichloromethane; 1: Grignard reaction / 2: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2011.03.154