ReH₇(PCH₃(C₆H₅)2)2

Base Information

Chemical Name:ReH₇(PCH₃(C₆H₅)2)2
CAS No.:79245-23-1
Molecular Formula:C₂₆H₃₃P₂Re
Molecular Weight:593.703
Hs Code.:

ReH<sub>7</sub>(PCH<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>)2)2

Synonyms:ReH₇(PCH₃(C₆H₅)2)2

Suppliers and Price of ReH₇(PCH₃(C₆H₅)2)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of ReH₇(PCH₃(C₆H₅)2)2

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of ReH₇(PCH₃(C₆H₅)2)2

There total 2 articles about ReH₇(PCH₃(C₆H₅)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 16940-66-2
sodium tetrahydroborate

: 144299-53-6,32025-94-8
ReCl₄(PMePh₂)2

: 79245-23-1
ReH₇(PCH₃(C₆H₅)2)2

Guidance literature:: In ethanol; byproducts: H2; NaBH4 was added to a suspn. of complex in EtOH, 10-20°C for 2.5 h (N2 atm.);; evapd., extd. with benzene, evapd. to dryness, ppt. was dissolved in THF, EtOH was added, concd. under vac. without heating, ppt. was filtered,dissoved in THF, EtOH was added, 12 h in refrigerator, filtered, washedwith MeOH;;
DOI:10.1021/ja00338a021

Reference yield:

: ReH₆Al(CH₃)2(P(C₆H₅)2CH₃)2

: 79245-23-1
ReH₇(PCH₃(C₆H₅)2)2

Guidance literature:: With H₂O; In water;
DOI:10.1021/ja00338a021

Reference yield: 60.0%

: 157072-60-1,61521-25-3,166941-05-5,16971-33-8
(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

: 79245-23-1
ReH₇(PCH₃(C₆H₅)2)2

: [(CO)(PMePh2)2Re(μ-H3)Ru(PPh3)3]

Guidance literature:: With KH; In tetrahydrofuran; byproducts: H2, Cl(1-); N2-atmosphere; stirring Re-complex with excess KH for 1 h, filtration, addn. to equimolar amt. of Ru-complex, stirring (40°C, 2 h); evapn., dissoln. in PhMe, chromy. (Al2O3, Et2O/hexane=5:1), evapn. (vac.), recrystn. (Et2O/hexane=5:1, 0°C); elem. anal.;
DOI:10.1016/0022-328X(94)05181-A