(S_p,S_c)-2-(trimethylsilyl)ethyl 3-<phosphinothioyl>-2-oxopropanoate

Base Information

Chemical Name:(S_p,S_c)-2-(trimethylsilyl)ethyl 3-<phosphinothioyl>-2-oxopropanoate
CAS No.:137792-53-1
Molecular Formula:C₁₇H₂₈NO₄PSSi
Molecular Weight:401.539
Hs Code.:

(S<sub>p</sub>,S<sub>c</sub>)-2-(trimethylsilyl)ethyl 3-<<methyl(1-phenylethyl)amino>phosphinothioyl>-2-oxopropanoate

Synonyms:(S_p,S_c)-2-(trimethylsilyl)ethyl 3-<phosphinothioyl>-2-oxopropanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S_p,S_c)-2-(trimethylsilyl)ethyl 3-<phosphinothioyl>-2-oxopropanoate

Chemical Property:

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Technology Process of (S_p,S_c)-2-(trimethylsilyl)ethyl 3-<phosphinothioyl>-2-oxopropanoate

There total 7 articles about (S_p,S_c)-2-(trimethylsilyl)ethyl 3-<phosphinothioyl>-2-oxopropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

: 122873-88-5
(S_p,S_c)-2-(trimethylsilyl)ethyl 3-<<2-(trimethylsilyl)ethoxy>phosphinothioyl>-2-oxopropanoate

: 137792-53-1
(S_p,S_c)-2-(trimethylsilyl)ethyl 3-<phosphinothioyl>-2-oxopropanoate

: C₁₇H₂₈NO₄PSSi

Guidance literature:: With 18-crown-6 ether; cesium fluoride; In acetonitrile; at 25 ℃; for 3h;
DOI:10.1021/jo00025a031

Reference yield:

: 19131-99-8
N-methyl-N-[(S)-1-phenylethyl]amine

: 137792-53-1
(S_p,S_c)-2-(trimethylsilyl)ethyl 3-<phosphinothioyl>-2-oxopropanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 34 percent / n-butyllithium / tetrahydrofuran / 5 h / -78 °C

2: 41 percent / n-butyllithium, cuprous iodide / tetrahydrofuran; diethyl ether; hexane / 7 h / -30 °C

3: 61 percent / CsF, 18-crown-6 / acetonitrile / 3 h / 25 °C

With copper(l) iodide; n-butyllithium; 18-crown-6 ether; cesium fluoride; In tetrahydrofuran; diethyl ether; hexane; acetonitrile;
DOI:10.1021/jo00025a031

Reference yield:

: 2916-68-9
2-(Trimethylsilyl)ethanol

: 137792-53-1
(S_p,S_c)-2-(trimethylsilyl)ethyl 3-<phosphinothioyl>-2-oxopropanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 62 percent / 15 h / 25 °C

2: 41 percent / n-butyllithium, cuprous iodide / tetrahydrofuran; diethyl ether; hexane / 7 h / -30 °C

3: 61 percent / CsF, 18-crown-6 / acetonitrile / 3 h / 25 °C

With copper(l) iodide; n-butyllithium; 18-crown-6 ether; cesium fluoride; In tetrahydrofuran; diethyl ether; hexane; acetonitrile;
DOI:10.1021/jo00025a031