phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside

Base Information

Chemical Name:phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside
CAS No.:945626-52-8
Molecular Formula:C₄₅H₄₃N₃O₁₅S
Molecular Weight:897.914
Hs Code.:

Synonyms:phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside

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Chemical Property of phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside

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Technology Process of phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside

There total 4 articles about phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 945626-51-7
phenyl 2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside

: 67817-15-6
Acetic acid (2R,3S,4R,5R,6R)-4-acetoxy-2-acetoxymethyl-5-azido-6-bromo-tetrahydro-pyran-3-yl ester

: 945626-52-8
phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside

Guidance literature:: With 2,4,6-trimethyl-pyridine; silver trifluoromethanesulfonate; In dichloromethane; at -30 ℃; for 2h;
DOI:10.1039/b618662a

Reference yield:

: 138857-53-1
phenyl 2,3-di-O-benzoyl-1-thio-β-D-galactoypyranoside

: 945626-52-8
phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.54 g / pyridine / 1 h / -30 °C

2: 76 percent / sym-collidine; silver triflate / CH₂Cl₂ / 2 h / -30 °C

With pyridine; 2,4,6-trimethyl-pyridine; silver trifluoromethanesulfonate; In dichloromethane;
DOI:10.1039/b618662a

Reference yield:

: 144830-21-7
phenyl 2,3-di-O-benzyl-4,6-di-O-benzylidene-1-thio-β-D-galactopyranoside

: 945626-52-8
phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-1-thio-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: aq. acetic acid / 4 h / 60 °C

2: 1.54 g / pyridine / 1 h / -30 °C

3: 76 percent / sym-collidine; silver triflate / CH₂Cl₂ / 2 h / -30 °C

With pyridine; 2,4,6-trimethyl-pyridine; silver trifluoromethanesulfonate; acetic acid; In dichloromethane;
DOI:10.1039/b618662a