ethyl ferrocenylphenylphosphinate

Base Information

Chemical Name:ethyl ferrocenylphenylphosphinate
CAS No.:847224-04-8
Molecular Formula:C₁₈H₁₉FeO₂P
Molecular Weight:354.168
Hs Code.:

Synonyms:ethyl ferrocenylphenylphosphinate

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Chemical Property of ethyl ferrocenylphenylphosphinate

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Technology Process of ethyl ferrocenylphenylphosphinate

There total 1 articles about ethyl ferrocenylphenylphosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 102-54-5,55404-68-7
ferrocene

: 5284-12-8
ethyl chloro(phenyl)phosphinate

: 847224-04-8
ethyl ferrocenylphenylphosphinate

Guidance literature:: With potassium tert-butylate; tert.-butyl lithium; In tetrahydrofuran; pentane; (Schlenk); dropwise addn. of a soln. of lithium compd. in pentane to a soln. of iron complex and potassium compd. in THF at -78°C, stirring for 30 min, addn. of phosphorus compd. in THF, warming to room temp.; addn. of 1M NaOH. extn. with CH2Cl2, drying org. phase with MgSO4, filtration, evapn. column chromy. (silica, CH2Cl2, then CH2Cl2/THF 7:3), evapn.; elem. anal.;
DOI:10.1016/j.jorganchem.2004.09.047

Reference yield: 92.0%

: 847224-04-8
ethyl ferrocenylphenylphosphinate

: 7732-18-5
water

: 847224-05-9
ferrocenyl(phenyl)phosphinic acid

Guidance literature:: With trimethylsilyl bromide; In dichloromethane; (Schlenk); dropwise addn. of silicon compd. to a soln. of iron complex in CH2Cl2, stirring overnight, addn. of water; filtration, washing ppt. with CH2Cl2 and Et2O; elem. anal.;
DOI:10.1016/j.jorganchem.2004.09.047