3-[4-(3-bromo-4-n-dodecyloxybenzoyloxy)-2-hydroxybenzylideneamino]phenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate

Base Information

• Chemical Name: 3-[4-(3-bromo-4-n-dodecyloxybenzoyloxy)-2-hydroxybenzylideneamino]phenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate
• CAS No.: 1373878-06-8
• Molecular Formula: C₅₈H₇₀BrNO₉
• Molecular Weight: 1005.1
• Mol file: 1373878-06-8.mol

Synonyms:3-[4-(3-bromo-4-n-dodecyloxybenzoyloxy)-2-hydroxybenzylideneamino]phenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate

Chemical Property of 3-[4-(3-bromo-4-n-dodecyloxybenzoyloxy)-2-hydroxybenzylideneamino]phenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-[4-(3-bromo-4-n-dodecyloxybenzoyloxy)-2-hydroxybenzylideneamino]phenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate

There total 9 articles about 3-[4-(3-bromo-4-n-dodecyloxybenzoyloxy)-2-hydroxybenzylideneamino]phenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

4-formyl-3-hydroxyphenyl 3-bromo-4-n-dodecyloxybenzoate (1373878-45-5) + 3-aminophenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate (936362-01-5) → 3-[4-(3-bromo-4-n-dodecyloxybenzoyloxy)-2-hydroxybenzylideneamino]phenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate (1373878-06-8)

Guidance literature:

With acetic acid; In ethanol; at 20 ℃; for 24h;

DOI:10.3762/bjoc.8.15

Reference yield:

C32H37NO7 → 3-[4-(3-bromo-4-n-dodecyloxybenzoyloxy)-2-hydroxybenzylideneamino]phenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate (1373878-06-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 10 wt % palladium on activated carbon; hydrogen / ethyl acetate

2: acetic acid / ethanol / 24 h / 20 °C

With 10 wt % palladium on activated carbon; hydrogen; acetic acid; In ethanol; ethyl acetate;

DOI:10.3762/bjoc.8.15

Reference yield:

p-dodecyloxybenzoic acid (2312-15-4) → 3-[4-(3-bromo-4-n-dodecyloxybenzoyloxy)-2-hydroxybenzylideneamino]phenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate (1373878-06-8)

Guidance literature:

Multi-step reaction with 5 steps

1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 24 h / 20 °C

2: dihydrogen peroxide; acetic acid / water / 22 h / 40 - 75 °C

3: dmap; dicyclohexyl-carbodiimide / dichloromethane / 24 h / 20 °C

4: 10 wt % palladium on activated carbon; hydrogen / ethyl acetate

5: acetic acid / ethanol / 24 h / 20 °C

With dmap; 10 wt % palladium on activated carbon; hydrogen; dihydrogen peroxide; acetic acid; dicyclohexyl-carbodiimide; In ethanol; dichloromethane; water; ethyl acetate;

DOI:10.3762/bjoc.8.15

upstream raw materials:

4-formyl-3-hydroxyphenyl 3-bromo-4-n-dodecyloxybenzoate

3-aminophenyl 4-(4-n-dodecyloxybenzoyloxy)benzoate

p-dodecyloxybenzoic acid

4-formylphenyl 4-(dodecyloxy)benzoate