[(R)-2-Benzylsulfanyl-1-(2-benzylsulfanyl-ethylcarbamoyl)-1-methyl-ethyl]-carbamic acid benzyl ester

Base Information

Chemical Name:[(R)-2-Benzylsulfanyl-1-(2-benzylsulfanyl-ethylcarbamoyl)-1-methyl-ethyl]-carbamic acid benzyl ester
CAS No.:177546-81-5
Molecular Formula:C₂₈H₃₂N₂O₃S₂
Molecular Weight:508.706
Hs Code.:

Synonyms:[(R)-2-Benzylsulfanyl-1-(2-benzylsulfanyl-ethylcarbamoyl)-1-methyl-ethyl]-carbamic acid benzyl ester

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Chemical Property of [(R)-2-Benzylsulfanyl-1-(2-benzylsulfanyl-ethylcarbamoyl)-1-methyl-ethyl]-carbamic acid benzyl ester

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Technology Process of [(R)-2-Benzylsulfanyl-1-(2-benzylsulfanyl-ethylcarbamoyl)-1-methyl-ethyl]-carbamic acid benzyl ester

There total 4 articles about [(R)-2-Benzylsulfanyl-1-(2-benzylsulfanyl-ethylcarbamoyl)-1-methyl-ethyl]-carbamic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 22572-33-4
S-benzylcysteamine hydrochloride

: 143564-91-4
N^α-benzyloxycarbonyl-S-benzyl-(R)-methylcysteine

: 177546-81-5
[(R)-2-Benzylsulfanyl-1-(2-benzylsulfanyl-ethylcarbamoyl)-1-methyl-ethyl]-carbamic acid benzyl ester

Guidance literature:: With 1-hydroxy-7-aza-benzotriazole; 2-chloro-1,3-dimethylimidazolidium hexafluorophosphate; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 25 ℃; for 1h;
DOI:10.1021/jo952285h

Reference yield:

: 15960-81-3
benzyl bromomethyl thioether

: 177546-81-5
[(R)-2-Benzylsulfanyl-1-(2-benzylsulfanyl-ethylcarbamoyl)-1-methyl-ethyl]-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) lithium diethylamide / 1.) THF, hexane, 40 min; other reagents: lithium diisopropylamide, lithium hexamethyldisilazide, dimethylpropyleneurea presence or absence, 2.) THF, hexane, 2 deg C, overnight

2: 1.0 g / LiOH*H₂O / tetrahydrofuran; H₂O / 25 °C

3: 99 percent / diisopropylethylamine, HOAt, 2-chloro-1,3-dimethylimidazolidium hexafluorophosphate / CH₂Cl₂ / 1 h / 25 °C

With lithium hydroxide; 1-hydroxy-7-aza-benzotriazole; 2-chloro-1,3-dimethylimidazolidium hexafluorophosphate; lithium diethylamide; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/jo952285h

Reference yield:

: 135923-86-3,135923-87-4,143564-89-0
(2R,4R)-3-<(Benzyloxy)carbonyl>-4-methyl-2-phenyl-1,3-oxazolidin-5-one

: 177546-81-5
[(R)-2-Benzylsulfanyl-1-(2-benzylsulfanyl-ethylcarbamoyl)-1-methyl-ethyl]-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) lithium diethylamide / 1.) THF, hexane, 40 min; other reagents: lithium diisopropylamide, lithium hexamethyldisilazide, dimethylpropyleneurea presence or absence, 2.) THF, hexane, 2 deg C, overnight

2: 1.0 g / LiOH*H₂O / tetrahydrofuran; H₂O / 25 °C

3: 99 percent / diisopropylethylamine, HOAt, 2-chloro-1,3-dimethylimidazolidium hexafluorophosphate / CH₂Cl₂ / 1 h / 25 °C

With lithium hydroxide; 1-hydroxy-7-aza-benzotriazole; 2-chloro-1,3-dimethylimidazolidium hexafluorophosphate; lithium diethylamide; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/jo952285h